89539-31-1

Basic information

• Product Name: methyl 2,3-di-O-benzoyl-4-O-benzyl-α-D-glucopyranoside
• Synonyms: methyl 2,3-di-O-benzoyl-4-O-benzyl-α-D-glucopyranoside
• CAS NO: 89539-31-1
• Molecular Weight: 492.526
• Mol File: 89539-31-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-benzoyl-4-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-benzoyl-4-O-benzyl-α-D-glucopyranoside(89539-31-1)
• EPA Substance Registry System: methyl 2,3-di-O-benzoyl-4-O-benzyl-α-D-glucopyranoside(89539-31-1)

Safety Data

• Hazardous Substances Data: 89539-31-1(Hazardous Substances Data)

Upstream product

• 97-30-3 methyl-alpha-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 6748-85-2 methyl 2,3-di-O-benzoyl-4,6-O-benzylidene-α-D-glucopyranoside 
• 98-88-4 benzoyl chloride 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 3162-96-7 methyl 4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 109923-11-7 methyl 4-O-benzyl-6-deoxy-2,3-di-O-p-tolylsulfonyl-α-D-glucopyranoside 
• 109923-12-8 methyl 2,3-anhydro-4-O-benzyl-6-deoxy-α-D-allopyranoside 
• 1415663-21-6 methyl 2-O-benzoyl-4-O-benzyl-3,6-dideoxy-3-dimethylamino-α-D-glucopyranoside 
• 1415663-22-7 1-O-acetyl-2-O-benzoyl-4-O-benzyl-3,6-dideoxy-3-dimethylamino-D-glucopyranose 
• 1415663-36-3 2-O-benzoyl-4-O-benzyl-3,6-dideoxy-3-dimethylamino-β-D-glucopyranosyl fluoride 
• 1415663-29-4 2-O-benzoyl-4-O-benzyl-3,6-dideoxy-3-dimethylamino-α-D-glucopyranosyl fluoride 
• 1415663-24-9 p-methylphenyl 2-O-benzoyl-4-O-benzyl-3,6-dideoxy-3-dimethylamino-1-thio-β-D-glucopyranoside 
• 1415663-25-0 C₂₂H₂₇NO₄S 
• 1415663-26-1 ethyl 2-O-benzoyl-3,6-dideoxy-3-dimethylamino-1-thio-β-D-glucopyranoside 
• 1415663-27-2 C₁₇H₂₅NO₄S 
• 1415663-28-3 2-O-benzoyl-4-O-benzyl-3,6-dideoxy-3-dimethylamino-α-D-glucopyranosyl trichloroacetimidate 
• 1415663-30-7 5-(2-O-benzoyl-4-O-benzyl-mycaminosyl)-3-O-descladinosyl-6-O-methyl-3-oxo-erythronolide A 11,12-cyclic carbonate 
• 1415663-31-8 5-(4-O-benzyl-mycaminosyl)-3-O-descladinosyl-6-O-methyl-3-oxo-erythronolide A?11,12-cyclic carbonate 
• 114827-98-4 Acetic acid (2S,3R,4S,5R,6R)-5-acetoxy-4-benzyloxy-2-((2R,3R,4R,5R,6S)-3-benzyloxy-5-hydroxy-6-methoxy-2-methyl-tetrahydro-pyran-4-yloxy)-6-methyl-tetrahydro-pyran-3-yl ester 

Relevant articles and documents

Cyanuric chloride/sodium borohydride: A new reagent combination for reductive opening of 4,6-benzylidene acetals of carbohydrates to primary alcohols

In the first such example, NaBH4 in combination with cyanuric chloride (TCT) has been used to obtain 6-hydroxy-4-benzyl ether derivatives from 4,6-benzylidene acetals of carbohydrates. The nature of hydride donor determines the regioselectivity

Some observations on the reductive ring opening of 4,6-O-benzylidene acetals of hexopyranosides with the borane trimethylamine-aluminium chloride reagent

Reductive ring openings of 3-O-benzoyl-4,6-O-benzylidene-d-glucopyranosides with BH3·NMe3-AlCl3 are accompanied by side reactions, such as debenzoylation and reduction of the benzoate to benzyl ether. This phenomenon was r

Regio- and chemoselective reductive cleavage of 4,6-O-benzylidene-type acetals of hexopyranosides using BH3·THF-TMSOTf

Benzylidene-type cyclic acetals of carbohydrates undergo efficient reductive ring opening using BH3·THF and a catalytic amount of TMSOTf at room temperature. 4,6-O-Benzylidene-hexopyranosides afford the corresponding 4-O-benzyl ethers exclusive