89618-93-9

Basic information

• Product Name: 2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate
• Synonyms: 2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate
• CAS NO: 89618-93-9
• Molecular Weight: 302.394
• Mol File: 89618-93-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate(89618-93-9)
• EPA Substance Registry System: 2-(4-methylphenyl)prop-2-en-1-yl 4-toluenesulfonate(89618-93-9)

Safety Data

• Hazardous Substances Data: 89618-93-9(Hazardous Substances Data)

Upstream product

• 42107-37-9 α-chloro-p-methylstyrene 
• 66520-90-9 2-(4-methylphenyl)-2-propen-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 89619-18-1 2-(4-methylphenyl)-1-(2,2,2-trifluoroethoxy)prop-2-ene 

Relevant articles and documents

Effect of the α-Trifluoromethyl Moiety on the Solvolysis of Allylic Sulfonates

A series of allylic sulfonates bearing aryl substituents on the 2-position and/or trifluoromethyl groups on the 1- and/or 3-positions has been studied under solvolytic conditions in 2,2,2-trifluoroethanol.Nonarylated 1,3-di(trifluoromethyl)-substituted allylic sulfonates did not solvolyze in a conventional manner but instead gave products diagnostic of a complex isomerization-cleavage process.Mono(trifluoromethyl)-substituted allylic sulfonates solvolyzed by normal paths to give kH/kCF3 ratios of 2E6 and 4E4 for the substitution at the 1- and 3-positions, respectively.No evidence for 1,3-? interactions was discerned.