897387-97-2

Basic information

• Product Name: (E)-2-styryl-tetrahydro-2H-pyran
• Synonyms: (E)-2-styryl-tetrahydro-2H-pyran
• CAS NO: 897387-97-2
• Molecular Weight: 188.269
• Mol File: 897387-97-2.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: (E)-2-styryl-tetrahydro-2H-pyran(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-2-styryl-tetrahydro-2H-pyran(897387-97-2)
• EPA Substance Registry System: (E)-2-styryl-tetrahydro-2H-pyran(897387-97-2)

Safety Data

• Hazardous Substances Data: 897387-97-2(Hazardous Substances Data)

Upstream product

• 1010081-55-6 (E)-1-phenylhept-2-ene-1,7-diol 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 142-68-7 TETRAHYDROPYRANE 
• 140-10-3 (E)-3-phenylacrylic acid 
• 536-74-3 phenylacetylene 
• 7217-71-2 1-phenyl-2-propenyl acetate 
• 1233145-06-6 C₁₅H₂₀O₃ 
• 100-52-7 benzaldehyde 
• 187471-70-1 2-(Diphenyl-phosphinoylmethyl)-tetrahydro-pyran 
• 5153-67-3 nitrostyrene 
• 335353-53-2 7-phenyl-hept-6-yn-1-ol 
• 80645-43-8 bromure de cinnamoyloxy-4 butyltriphenylphosphonium 
• 147492-30-6 1-Phenyl-3,7-dihydroxy-hepten-⁽¹⁾ 
• 103-64-0 bromostyrene 

Relevant articles and documents

Photoredox Oxo-C(sp3)-H Bond Functionalization via in Situ Cu(I)-Acetylide Catalysis

A unified strategy for the synthesis of 2-vinyl heterocycles is reported. With visible light irradiation, simple and cheap CuCl is able to functionalize a terminal alkyne, giving Cu(I)-acetylide in situ. Unlike the case of noble metals or organic dye photocatalysts, this critical Cu(I)-acetylide not only activates the C-H bond of terminal alkynes but also serves as a photocatalyst to achieve varieties of 2-vinyl heterocycles in good to excellent yields, even for large scale and late-stage functionalization of natural product.

Visible-Light-Mediated Oxidative Decarboxylative Coupling of Cinnamic Acid Derivatives with Tetrahydrofuran

A visible-light-mediated protocol for direct oxidative decarboxylative coupling of various cinnamic acid derivatives with tetrahydrofuran was developed, leading to simple preparations of a range of vinyltetrahydrofurans under operationally mild and conven

Iron-catalyzed alkenylation of cyclic ethers via decarboxylative sp 3(C)-sp2(C) coupling

An efficient Fe(acac)3-catalyzed decarboxylative C(sp 2)-C(sp3) coupling reaction via oxidation of C-H bond adjacent to an oxygen atom has been developed successfully, in which cyclic ethers are selectively transformed into the corresponding alkenylation products with good chemical yields and excellent stereoselectivities. The mechanism was studied and the reaction was supposed to proceed through a radical oxidative coupling process.