89882-22-4Relevant articles and documents
The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent To a Stereogenic Centre: Diastereoselective Alkylation and Protonation of Open-chain Enolates Having a Stereogenic Centre Carrying a Silyl Group at the β Position
Crump, Roger A. N. C.,Fleming, Ian,Hill, John H. M.,Parker, David,Reddy, N. Laxma,Waterson, David
, p. 3277 - 3294 (2007/10/02)
The alkylation and protonation of enolates having a β-silyl group, prepared by conjugate addition of a silyl-cuprate reagent to enone systems, are almost always highly diastereoselective in the sense 3 in a wide variety of reactions.The effects of varying
A Synthesis of Allylsilanes in which the Silyl Group is at the More-substituted End of the Allyl Group
Fleming, Ian,Waterson, David
, p. 1809 - 1813 (2007/10/02)
The allylsilanes (8), (11), (18) - (20), and (26), have been made by a three-step sequence from αβ-unsaturated esters.The steps are conjugate addition of the phenyldimethylsilyl group, lithium aluminium hydride reduction, and selenium-mediated dehydration
