89882-25-7

Basic information

• Product Name: ethyl (2RS,3SR)-3-dimethyl(phenyl)silyl-2-methylbutanoate
• CAS NO: 89882-25-7
• Molecular Weight: 264.44
• Mol File: 89882-25-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: ethyl (2RS,3SR)-3-dimethyl(phenyl)silyl-2-methylbutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2RS,3SR)-3-dimethyl(phenyl)silyl-2-methylbutanoate(89882-25-7)
• EPA Substance Registry System: ethyl (2RS,3SR)-3-dimethyl(phenyl)silyl-2-methylbutanoate(89882-25-7)

Safety Data

• Hazardous Substances Data: 89882-25-7(Hazardous Substances Data)

Upstream product

• 6776-19-8 ethyl (Z)-crotonate 
• 75583-57-2 lithium bis(dimethyl(phenyl)silyl)cuprate 
• 74-88-4 methyl iodide 
• 3839-31-4 dimethyl(phenyl)silyllithium 
• 623-70-1 ethyl (E)-crotonate 

Relevant articles and documents

The Diastereoselectivity of Electrophilic Attack on Trigonal Carbon Adjacent To a Stereogenic Centre: Diastereoselective Alkylation and Protonation of Open-chain Enolates Having a Stereogenic Centre Carrying a Silyl Group at the β Position

The alkylation and protonation of enolates having a β-silyl group, prepared by conjugate addition of a silyl-cuprate reagent to enone systems, are almost always highly diastereoselective in the sense 3 in a wide variety of reactions.The effects of varying

Diastereoselectivity in the Alkylation of Enolates having an Adjacent Silyl Group

The methylation of open-chain enolates having an adjacent silyl group is highly diastereoselective in favour of the isomer (2) having the silyl and methyl groups trans on the carbon chain; protonation of the corresponding enolate, already carrying the methyl group, gives the other diastereoisomer (3), but with somewhat lower diastereoselectivity.