90150-05-3

Basic information

• Product Name: N-(CYCLOHEXYLMETHYL)DIETHYL AMINO
• Synonyms: N-(CYCLOHEXYLMETHYL)DIETHYL AMINO;(CyclohexylMethyl)diethylaMine, 97%
• CAS NO: 90150-05-3
• Molecular Formula: C₁₁H₂₃N
• Molecular Weight: 168.29908
• Mol File: 90150-05-3.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 101-104℃/28mm
• Appearance: /
• Refractive Index: 1.4555
• CAS DataBase Reference: N-(CYCLOHEXYLMETHYL)DIETHYL AMINO(CAS DataBase Reference)
• NIST Chemistry Reference: N-(CYCLOHEXYLMETHYL)DIETHYL AMINO(90150-05-3)
• EPA Substance Registry System: N-(CYCLOHEXYLMETHYL)DIETHYL AMINO(90150-05-3)

Safety Data

• HazardClass: 8
• Hazardous Substances Data: 90150-05-3(Hazardous Substances Data)

Usage

General Description

N-(cyclohexylmethyl)diethylamino is a chemical compound with the molecular formula C14H29N. It is an organic compound that contains both a cyclohexyl and diethylamino functional group. The compound is commonly used as a reagent in organic chemistry for various reactions, including the synthesis of pharmaceuticals and other organic compounds. Its unique structure and properties make it a versatile and useful compound in chemical synthesis and research. It is important to handle this chemical with care due to its potential hazards and the need for proper safety precautions during handling and storage.

Upstream product

• 64847-82-1 cyclohexylmethylene diacetate 
• 109-89-7 diethylamine 
• 5461-52-9 N,N-diethylcyclohexanecarboxamide 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 64-17-5 ethanol 
• 124-38-9 carbon dioxide 
• 110-83-8 cyclohexene 
• 3218-02-8 cyclohexylmethylamine 
• 75-05-8 acetonitrile 
• 13686-66-3 N,N-diethylaminodimethylsilane 
• 2043-61-0 cyclohexanecarbaldehyde 
• 2550-36-9 Cyclohexylmethyl bromide 

Relevant articles and documents

Atomically dispersed Rh on hydroxyapatite as an effective catalyst for tandem hydroaminomethylation of olefins

Tandem hydroaminomethylation is an efficient and green route for one-pot synthesis of amines directly from olefins. Herein, heterogeneous hydroxyapatite (HAP) supported single-atom Rh catalyst was prepared and used for tandem hydroaminomethylation of olefins. Characterization techniques confirmed the atomic dispersion of Rh species on HAP. Up to 99% conversion of 1-hexene with high selectivity to the desired amines (93.2%) was obtained over 0.5Rh1/HAP catalyst. Mechanism study demonstrated that the first hydroformylation step during the tandem catalytic process was rate-determining. Compared with the Rh nanoparticles on other oxide supports (Mg3Al, MgO and Al2O3), the atomically dispersed Rh sites on HAP ensured the high hydroformylation activity, thereby guaranteed the outstanding catalytic performance for the total tandem process. Furthermore, various corresponding amines can be obtained with satisfactory yields over 0.5Rh1/HAP catalyst from a wide scope of olefins or amines substrates.

NEW METHOD FOR THE SYNTHESIS OF UNSYMMETRICAL TERTIARY AMINES

Disclosed is a new method for the synthesis of unsymmetrical tertiary amines using alcohol and an imine, and to new tertiary amines.

Carbon dioxide transformation in imidazolium salts: Hydroaminomethylation catalyzed by Ru-complexes

The catalytic species generated by dissolving Ru3(CO)12 in the ionic liquids 1-n-butyl-3-methyl-imidazolium chloride or 1-n-butyl-2,3-dimethyl-imidazolium chloride are efficient multifunctional catalysts for: (a) reverse water-gas shift, (b) hydroformylation of alkenes, and (c) reductive amination of aldehydes. Thus the reaction of alkenes with primary or secondary amines (alkene/amine, 1:1) under CO2/H2 (1:1) affords the hydroamino-methylations products in high alkene conversions (up to 99%) and selectivities (up to 96%). The reaction proceeds under relatively mild reaction conditions (120 °C, 60 bar = 6 MPa) and affords selectively secondary and tertiary amines. The presence of amine strongly reduces the alkene hydrogenation competitive pathway usually observed in the hydroformylation of terminal alkenes by Ru complexes. The catalytic system is also highly active for the reductive amination of aldehydes and ketones yielding amines in high yields (> 90%).