90311-23-2

Basic information

• Product Name: 9-SC₆H₅-1.7-C₂B₁₀H₁₁
• Synonyms: 9-SC₆H₅-1.7-C₂B₁₀H₁₁
• CAS NO: 90311-23-2
• Molecular Weight: 252.391
• Mol File: 90311-23-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-SC₆H₅-1.7-C₂B₁₀H₁₁(CAS DataBase Reference)
• NIST Chemistry Reference: 9-SC₆H₅-1.7-C₂B₁₀H₁₁(90311-23-2)
• EPA Substance Registry System: 9-SC₆H₅-1.7-C₂B₁₀H₁₁(90311-23-2)

Safety Data

• Hazardous Substances Data: 90311-23-2(Hazardous Substances Data)

Upstream product

• 90311-18-5 9-m-carboranyl sulfenylchloride 
• 100-58-3 phenylmagnesium bromide 
• 17157-02-7 9-iodo-m-carborane 
• 930-69-8 sodium thiophenolate 

Downstream Products

• 90311-30-1 phenyl(9-m-carboranylthio)sulfone 
• 90311-29-8 phenyl(9-m-carboranylthio)sulfoxide 

Relevant articles and documents

A NEW SIMPLE METHOD FOR THE PRODUCTION AND SOME CONVERSIONS OF B-S BOND-CONTAINING o- AND m-CARBORANYL

A new method of synthesis of o- and m-carboranyl-B-thiols and o- and m-carboranyl-B,B'-dithiols via the electrophilic sulfuration of o-, m-carboranes with S2Cl2 in the presence of AlCl3 is described.The reaction of o-carborane with excess S2Cl2 in the presence of AlCl3 gives B,B',B'',B'''-tetrathiol-o-carborane.Various chemical conversions of carborane sulfur derivatives are studied.A description is made of carbonyl derivatives of di-, tetra- and hexavalent sulfur, such as sulfenyl chlorides, thiocyanates, disulfides, alkyl- and aryl sulfides, aryl sulfones and aryl sulfoxides. 9-m-Carboranylsulfinic acid was found to readily disproportionate to thiosulfonate and sulfonic acid.The chemical behaviour of o- and m-carboranyl sulfur derivatives in which the sulfur is ?-bound to the six-coordinated boron atom was also found to be similar to that of organic sulfur derivatives.