90331-02-5

Basic information

• Product Name: C₁₃H₁₇NO
• CAS NO: 90331-02-5
• Molecular Weight: 203.284
• Mol File: 90331-02-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: C₁₃H₁₇NO(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₃H₁₇NO(90331-02-5)
• EPA Substance Registry System: C₁₃H₁₇NO(90331-02-5)

Safety Data

• Hazardous Substances Data: 90331-02-5(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 594-70-7 2-Methyl-2-nitropropane 
• 57497-39-9 N-tertbutylhydroxylamine hydrochloride 
• 136809-07-9 1-tert-butyl-4-phenyl-1-aza-1,3-butadiene 
• 114655-48-0 (E)-2-methyl-N-((E)-3-phenylallylidene)propan-2-amine 
• 90330-97-5 (E)-2-(tert-butyl)-3-styryl-1,2-oxaziridine 

Downstream Products

• 1152672-26-8 (5-butyl-2-tert-butyl-3-styryl-2,3-dihydro-isoxazol-4-yl)-phenyl-methanone 
• 1383738-71-3 (S,E)-2-tert-butyl-5-phenyl-3-styryl-2,3-dihydroisoxazole-4-carbaldehyde 

Relevant articles and documents

Stereoselective synthesis of fluoroalkenoates and fluorinated isoxazolidinones: N-substituents governing the dual reactivity of nitrones

α-Fluoroalkenoates and 4-fluoro-5-isoxazolidinones are of vast interest due to their potential biological applications. We now demonstrate the syntheses of (E)-α-fluoroalkenoates and 4-fluoro-5-isoxazolidinones by the reactions between nitrones and α-fluoro-α-bromoacetate. By altering N-substituents in nitrones, (E)-α-fluoroalkenoates and 4-fluoro-5-isoxazolidinones can be achieved, respectively, with high chemo- and stereoselectivities. Experimental and computational studies have been conducted to elucidate the reaction mechanisms. Linear free energy relationship studies further revealed that the N-substituent effects are primarily of electronic origin. Copyright

Nitrone derivatives

A compound represented by the figure (1) or a pharmaceutically acceptable salt thereof is useful as medicament for treating retinal degenerative disorders: wherein Ar is optionally substitued phenyl or optionally substituted heteroaryl;. n is 0, 1 or 2; W

1-AZADIENES AS A SYNTHON FOR HETEROCYCLIC SYNTHESIS

1-Azabutadienes 1 were found to be a good building block for three- to five-membered heterocycles having a functional group.Oxidation of 1 with mCPBA afforded 3-alkenyloxaziridines 2.Cycloaddition of 1 with ketenes gave the 4-alkenylazetidinones 6.Addition of a nitrile imine occured across the C=N bond to give the 3-alkenyltriazoline 8, while that of a nitrile ylide occurred on the C=C bond to give the 3-formylpyrrole 14 formed by hydrolysis of the C=N bond.