90458-95-0

Basic information

• Product Name: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-
• CAS NO: 90458-95-0
• Molecular Formula: C15H24
• Molecular Weight: 204.356
• Mol File: 90458-95-0.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-(90458-95-0)
• EPA Substance Registry System: Cyclohexene, 4-(1,5-dimethyl-4-hexenylidene)-1-methyl-(90458-95-0)

Safety Data

• Hazardous Substances Data: 90458-95-0(Hazardous Substances Data)

Upstream product

• 3790-71-4 (2Z,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol 
• 40716-66-3 (E)-3,7,11-trimethyl-1,6,10-dodecatrien-3-ol 
• 58193-73-0 4-(1,5-dimethyl-4-hexenylidene)-1-cyclohexanone 
• 515-69-5 bisabolol 
• 106-28-5 Farnesol 
• 138-86-3 limonene. 
• 29548-14-9 α-4-dimethyl-3-cyclohexene-1-acetaldehyde 
• 89487-33-2 prenylmagnesium bromide 
• 7212-44-4 (+/-)-nerolidol 
• 4426-72-6 hydrazine carboxamide 
• 58193-74-1 2-Methyl-6-(4'-hydroxy-4'-methylcyclohexyliden)-hept-2-en 
• 111-02-4 squalene 
• 40716-67-4 (3RS)-nerolidyl diphosphate 
• 3796-70-1 trans geranyl acetone 

Downstream Products

• 110-15-6 succinic acid 
• 123-76-2 levulinic acid 
• 67-64-1 acetone 
• 100-21-0 terephthalic acid 

Relevant articles and documents

FIRST STEREOSPECIFIC SYNTHESIS OF E-γ-BISABOLENE. A METHOD FOR THE CONCURRENT GENERATION OF A RING AND A TETRASUBSTITUTED EXOCYCLIC DOUBLE BOND.

A short stereospecific synthesis of E-γ-bisabolene (1) from an acyclic acetylenic precursor (either 2 or 6) is described.

Stereochemical investigations on the biosynthesis of achiral (Z)-γ-bisabolene in Cryptosporangium arvum

A newly identified bacterial (Z)-γ-bisabolene synthase was used for investigating the cyclisation mechanism of the sesquiterpene. Since the stereoinformation of both chiral putative intermediates, nerolidyl diphosphate (NPP) and the bisabolyl cation, is lost during formation of the achiral product, the intriguing question of their absolute configurations was addressed by incubating both enantiomers of NPP with the recombinant enzyme, which resolved in an exclusive cyclisation of (R)-NPP, while (S)-NPP that is non-natural to the (Z)-γ-bisabolene synthase was specifically converted into (E)-β-farnesene. A hypothetical enzyme mechanistic model that explains these observations is presented.

METHOD FOR THE PRODUCTION OF ALPHA-BISABOLOL FROM NEROLIDOL

The invention relates to a method for the production of alpha-bisabolol, consiting of the following step: nerolidol is reacted with a mixture of ketone, sulfonic acid and perchloric acid.