90711-96-9

Basic information

• Product Name: [1,3]DIOXOLAN-2-YL-ACETALDEHYDE
• Synonyms: [1,3]DIOXOLAN-2-YL-ACETALDEHYDE;2-(1,3-Dioxolan-2-yl)acetaldehyde
• CAS NO: 90711-96-9
• Molecular Formula: C₅H₈O₃
• Molecular Weight: 116.12
• Mol File: 90711-96-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 183.7±15.0 °C(Predicted)
• Appearance: /
• Density: 1.098±0.06 g/cm3(Predicted)
• CAS DataBase Reference: [1,3]DIOXOLAN-2-YL-ACETALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: [1,3]DIOXOLAN-2-YL-ACETALDEHYDE(90711-96-9)
• EPA Substance Registry System: [1,3]DIOXOLAN-2-YL-ACETALDEHYDE(90711-96-9)

Safety Data

• Hazardous Substances Data: 90711-96-9(Hazardous Substances Data)

Usage

General Description

[1,3]Dioxolan-2-yl-acetaldehyde, also known as dioxolan-2-yl acetaldehyde, is a chemical compound with the molecular formula C5H8O3. It is a colorless liquid with a fruity odor and is commonly used as an intermediate in the synthesis of pharmaceuticals and other organic compounds. The compound is also used in the production of flavors and fragrances, as well as in the manufacturing of polymers and plastics. It is important to handle and store [1,3]dioxolan-2-yl-acetaldehyde with care, as it is flammable and can be harmful if ingested or inhaled. Additionally, it should be kept away from sources of ignition and incompatible materials.

Upstream product

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Relevant articles and documents

Synthesis of regio- and stereoselectively deuterium-labelled derivatives of l-glutamate semialdehyde for studies on carbapenem biosynthesis

l-Glutamate semialdehyde (l-GSA) is an intermediate in biosynthetic pathways including those leading to the carbapenem antibiotics. We describe studies on asymmetric deuteration or hydrogenation of appropriate didehydro-amino acid precursors for the stereoselective synthesis of C-2- and/or C-3-[2H]-labelled l-GSA suitable for use in mechanistic studies. Regioselective deuterium incorporation into the 5-position of l-GSA was achieved using a labelled form of the Schwartz reagent (Cp2Zr 2HCl). 4,4-Dideuterated and fully backbone deuterated l-GSAs were prepared. The application of the labelled l-GSA derivatives to biosynthetic studies was exemplified by the chemo-enzymatic preparation of selectively deuterated trans-carboxymethylprolines using two different carboxymethylproline synthases (CarB and ThnE), enzymes that catalyse early steps in the biosynthesis of two carbapenems: (5R)-carbapenem-3-carboxylate and thienamycin, respectively. The Royal Society of Chemistry 2009.

Novel pesticides, preparation and use

The specification describes and claims methods of controlling acarine pests by application of a compound of Formula (I), methods of controlling arthropod pests by application of a compound of Formula (IA), compounds of Formula (IA) per se, pesticidal compositions comprising a compound of Formula (IA), and processes for preparing a compound of Formula (IA).

Synthesis and Use of 7-Substituted Norbornadienes for the Preparation of Prostaglandins and Prostanoids

Syntheses of 7-substituted norbornadienes from 7-t-butoxy- and 7-halogeno-norbornadienes are described.Rearrangement of the products in the presence of peracetic acid gives bicyclic aldehydes (2) in equilibrium with enol ethers (3) which are hydrolysed to hydroxycyclopentenylacetaldehydes (4), and converted into key intermediates for the synthesis of prostaglandins and their analogues.Syntheses of prostaglandin J analogues with n-hexyl and phenyl groups replacing the ο-side-chain are described.