90719-27-0

Basic information

• Product Name: 2-Oxazolidinone, 3-(1-oxo-2-propenyl)-4-(phenylmethyl)-, (S)-
• CAS NO: 90719-27-0
• Molecular Formula: C13H13NO3
• Molecular Weight: 231.251
• Mol File: 90719-27-0.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 2-Oxazolidinone, 3-(1-oxo-2-propenyl)-4-(phenylmethyl)-, (S)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone, 3-(1-oxo-2-propenyl)-4-(phenylmethyl)-, (S)-(90719-27-0)
• EPA Substance Registry System: 2-Oxazolidinone, 3-(1-oxo-2-propenyl)-4-(phenylmethyl)-, (S)-(90719-27-0)

Safety Data

• Hazardous Substances Data: 90719-27-0(Hazardous Substances Data)

Upstream product

• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 79-10-7 acrylic acid 
• 814-68-6 acryloyl chloride 
• 3182-95-4 L-Phenylalaninol 
• 335223-27-3 C₈H₁₂O₄ 
• 145941-30-6 acrylic pivalic anhydride 
• 2051-76-5 acrylic acid anhydride 
• 40217-17-2 (R)-4-(phenylmethyl)-2-oxazolidinone 
• 90719-32-7 4-benzyl-2-oxazolidinone 
• 770738-36-8 (R)-4-benzyl-3-{3-[(iodomethyl)dimethylsilyl]propanoyl}-1,3-oxazolidin-2-one 
• 770738-35-7 (R)-4-benzyl-3-{3-[(chloromethyl)dimethylsilyl]propanoyl}-1,3-oxazolidin-2-one 
• 770738-39-1 2-[({3-[(4R)-4-benzyl-2-oxo-1,3-oxazolidin-3-yl]-3-oxopropyl}dimethylsilyl)methyl]-1H-isoindole-1,3(2H)-dione 

Downstream Products

• 90719-34-9 (4S)-3-((3'R,4'R,6'R)-bicyclo[2.2.1]heptene-4'-carbonyl)-4-(phenylmethyl)-2-oxazolidinone 
• 878003-15-7 4-benzyl-3-(5-triisopropylsilanyloxypent-2-enoyl)oxazolidin-2-one 
• 1131125-95-5 4-benzyl-3-[3-fluoro-2-(phenylselenyl)propanoyl]oxazolidin-2-one 
• 1226966-85-3 C₁₉H₁₉NO₃Se 
• 1359067-59-6 C₂₅H₂₄N₂O₅ 
• 1359067-54-1 C₂₅H₂₄N₂O₅ 
• 1359067-38-1 C₂₅H₂₄N₂O₅ 
• 150493-32-6 (S)-4-Benzyl-3-((1S,2S,4S)-bicyclo[2.2.1]hept-5-ene-2-carbonyl)-oxazolidin-2-one 
• 134178-51-1 (4S)-3-(4-(1-cyclohexenyl)-1-oxopentyl)-4-(phenylmethyl)-2-oxazolidinone 
• 134178-54-4 (4S)-3-(4,6,6-trimethyl-5-methylene-1-oxoheptyl)-4-(phenylmethyl)-2-oxazolidinone 
• 134178-53-3 (4S)-3-(4,6,6-trimethyl-5-methylene-1-oxoheptyl)-4-(phenylmethyl)-2-oxazolidinone 
• 134178-53-3 (4S)-3-(4,6,6-trimethyl-5-methylene-1-oxoheptyl)-4-(phenylmethyl)-2-oxazolidinone 
• 1414348-89-2 (S)-4-benzyl-3-(4,5,5,5-tetrafluoro-4-(trifluoromethyl)pentanoyl)-oxazolidin-2-one 
• 1414348-88-1 (S)-4-benzyl-3-(4,4,5,5,6,6,7,7,7-nonafluoroheptanoyl)oxazolidin-2-one 

Relevant articles and documents

Silent catalytic promiscuity in the high-fidelity terpene cyclase δ-cadinene synthase

δ-Cadinene synthase (DCS) is a high-fidelity sesquiterpene synthase that generates δ-cadinene as the sole detectable organic product from its natural substrate (E,E)-FDP. Previous work with this enzyme using substrate analogues revealed the ability of DCS

Asymmetric synthesis of isoquinuclidines by Diels-Alder reaction of 1,2-dihydropyridine utilizing a chiral Lewis acid catalyst

The chiral isoquinuclidine derivative, 2-azabicyclo[2.2.2]octane ring system, endo-(7R)-3 was obtained in good yield with excellent diastereoselectivity (up to 92% de) by Diels-Alder reaction of 1-(phenoxycarbonyl)-1,2-dihydropyridine 1 with N-acryloyl-(4S)-4- benzyloxazolidin-2-one (4S)-2 using titanium-(2R,3R)-TADDOLate 4 as a chiral Lewis acid catalyst in toluene at 0 °C. On the other hand, endo-(7S)-3 was obtained in good yield with excellent diastereoselectivity (up to 97% de) by Diels-Alder reaction of 1 with (4R)-2 using Cu(OTf)2/(4S,4′S)- bis(oxazoline) catalyst 8 as a chiral Lewis acid catalyst in dichloromethane at 0 °C. In these reactions, the choice of solvent and the combination of titanium-(2R,3R)-TADDOLate 4 {or Cu(II)/(4S,4′S)-bis(oxazoline) 8} and dienophile (4S)-2 {or (4R)-2} are very important. The stereochemistry of endo-(7R)-3 has been established to be (1R,4S,7R) and the reaction mechanism is proposed.

Diastereoselective aziridination of chiral electron-deficient olefins with N-chloro-N-sodiocarbamates catalyzed by chiral quaternary ammonium salts

Chiral quaternary ammonium salt-catalyzed diastereoselective aziridination of electron-deficient olefins that possess a chiral auxiliary with N-chloro-N-sodiocarbamates was developed. The key to high stereoselectivity was found to be the employment of the