908142-25-6

Basic information

• Product Name: 1-2 O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose
• Synonyms: 1-2 O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose
• CAS NO: 908142-25-6
• Molecular Weight: 310.347
• Mol File: 908142-25-6.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 1-2 O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1-2 O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose(908142-25-6)
• EPA Substance Registry System: 1-2 O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose(908142-25-6)

Safety Data

• Hazardous Substances Data: 908142-25-6(Hazardous Substances Data)

Upstream product

• 591727-19-4 1-2,5-6 di-O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose 
• 100-44-7 benzyl chloride 
• 350255-13-9 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 100-39-0 benzyl bromide 

Downstream Products

• 1244773-09-8 C₁₈H₂₄O₆ 
• 1323207-86-8 benzyl (3S,4S,5R)-3,4-diacetoxy-5-(tri-O-acetyl-β-D-xylopyranosyloxy)piperidine-1-carboxylate 
• 1323207-91-5 benzyl (3S,4S,5R)-3,4-diacetoxy-5-[tri-O-acetyl-β-D-xylopyranosyl-(1->4)-di-O-acetyl-β-D-xylosyl-(1->4)-di-O-acetyl-β-D-xylosyloxy]piperidine-1-carboxylate 
• 69177-83-9 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-nitro-α-D-xylo-hex-5-enofuranose 
• 13042-55-2 1,5-Dideoxy-1,5-iminoxylitol 
• 41545-33-9 3-O-benzyl-6-deoxy-1,2-O-isopropylidene-6-C-nitro-α-L-idofuranose 
• 99784-35-7 3-O-benzyl-5,6-dideoxy-6-C-nitro-α-D-xylo-hexanofuranose 
• 99784-36-8 (2S,3R)-2-(benzyloxy)-3-(formyloxy)-5-nitropentanal 
• 99784-34-6 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-6-C-nitro-α-D-xylo-hexanofuranose 
• 72277-35-1 (1R,2R,3S,4R)-methyl [3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-gluco]heptfuran-5-enuronate 

Relevant articles and documents

Metal-free [3+2] cycloaddition of glycosyl olefinic ester with in situ generated CF3CHN2: Access to CF3-substituted pyrazoline glycoconjugates

An efficient [3 + 2] cycloaddition of glycosyl olefinic ester with in situ generated CF3CHN2 for the syntheses of CF3-substituted pyrazoline glycoconjugate has been developed. This mild, one-pot reaction condition avoiding the use of metallic catalyst and additive will be useful in the pharmaceutical industry. This reaction features are the broad substrate scope, good functional group tolerance with good to high yields.

MODIFIED NUCLEOSIDE PHOSPHORAMIDITES

The present disclosure relates to compounds and compositions containing 5'-phosphoramidite nucleoside monomers of formulae (I) and (II), and methods of making and use, wherein the substituents are as defined in the appended claims.

I2/PPh3-mediated facile synthesis of glycoconjugated N-acylbenzotriazoles

A well-stabilized method for synthesis of N-acylbenzotriazoles from carboxylic acids using I2/PPh3 in anhydrous dichloromethane has been extended in glycochemistry to synthesize glycoconjugated N-acylbenzotriazoles with high yields at room temperature in 2-hour reaction time.