908331-52-2

Basic information

• Product Name: (1R)-menthyl (1S,2S)-(+)-1,3,3-d³-2-phenylcyclopropanecarboxylate
• CAS NO: 908331-52-2
• Molecular Weight: 303.417
• Mol File: 908331-52-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1R)-menthyl (1S,2S)-(+)-1,3,3-d³-2-phenylcyclopropanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: (1R)-menthyl (1S,2S)-(+)-1,3,3-d³-2-phenylcyclopropanecarboxylate(908331-52-2)
• EPA Substance Registry System: (1R)-menthyl (1S,2S)-(+)-1,3,3-d³-2-phenylcyclopropanecarboxylate(908331-52-2)

Safety Data

• Hazardous Substances Data: 908331-52-2(Hazardous Substances Data)

Upstream product

• 908331-49-7 (1R,2S,5R)-(-)-menthyl α-²H-diazoacetate 
• 934-85-0 styrene-d2 

Relevant articles and documents

Efficient syntheses of four stable-isotope labeled (1R)-menthyl (1S,2S)-(+)-2-phenylcyclopropanecarboxylates

Many carbenoid cyclopropanation reactions promoted by chiral catalysts give product mixtures reflecting impressive diastereo- and enantioselectivities. Few provide a single chiral product efficiently. This limitation has been overcome in cyclopropanations of styrene and isotopically labeled styrenes with α-diazoacetates. Convenient syntheses on a 20 g scale of each of four chiral isotopically labeled (1R)-menthyl (1S,2S)-2- phenylcyclopropanecarboxylates (the 1-d-3-13C, 1,(3S)-d2, 1,2,(3S)-d3, and 1,3,3-d3 isotopomers) of better than 99% ee have been realized. The Royal Society of Chemistry 2006.