91076-08-3

Basic information

• Product Name: Zinc, bis(dimethylphenylsilyl)-
• CAS NO: 91076-08-3
• Molecular Formula: C16H22Si2Zn
• Molecular Weight: 335.912
• Mol File: 91076-08-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Zinc, bis(dimethylphenylsilyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Zinc, bis(dimethylphenylsilyl)-(91076-08-3)
• EPA Substance Registry System: Zinc, bis(dimethylphenylsilyl)-(91076-08-3)

Safety Data

• Hazardous Substances Data: 91076-08-3(Hazardous Substances Data)

Upstream product

• 768-33-2 phenyldimethylsilyl chloride 
• 7646-85-7 zinc(II) chloride 
• 25149-72-8 dimethylphenylgermyllithium 
• 7699-45-8 zinc dibromide 
• 3839-31-4 dimethyl(phenyl)silyllithium 

Downstream Products

• 91076-06-1 1-dimethylphenylsilyl-1-cyclononene 
• 91076-07-2 3-dimethylphenylsilyl-1-cyclononene 
• 63972-14-5 1-(dimethylphenylsilyl)-3-methyl-2-butene 
• 146513-23-7 dimethyl(cyclohex-2-en-1-yl)(phenyl)silane 
• 79294-34-1 (E)-3-dimethyl(phenyl)silyl-1-phenyl-1-propene 
• 79753-67-6 (2-cyclohexylidene-ethyl)dimethyl(phenyl)silane 
• 89634-21-9 cis dimethyl(5-methylcyclohex-2-enyl)phenylsilane 
• 89634-21-9 (RS,SR)-dimethyl(5-methylcyclohex-2-en-1-yl)(phenyl)silane 
• 118356-60-8 3-(dimethyl(phenyl)silyl)-1,3-diphenylpropan-1-one 
• 114431-81-1 3-(dimethyl(phenyl)silyl)methyl butanoate 
• 67263-05-2 ethyl 3-(dimethyl(phenyl)silyl)-3-phenylpropionate 
• 803731-35-3 3-dimethylphenylsilyl-4,4-dimethylcyclohexanone 

Relevant articles and documents

Total Synthesis of Leiodermatolide A via Transfer Hydrogenative Allylation, Crotylation, and Propargylation: Polyketide Construction beyond Discrete Allyl- or Allenylmetal Reagents

The total synthesis of leiodermatolide A was accomplished in 13 steps (LLS). Transfer hydrogenative variants of three carbonyl additions that traditionally rely on premetalated reagents (allylation, crotylation, and propargylation) are deployed together i

Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes

Zinc reagents (Me2PhSi)2Zn and [(Me3Si)3Si]2Zn undergo highly regio- and stereoselective addition across the carbon-carbon triple bond of nitrogen-, sulfur-, oxygen-, and phosphorus-substituted termin

Preparation and structural characterization of trimethylsilyl-substituted germylzinc halides, (Me3Si)3GeZnX (X = Cl, Br, and I) and silylzinc chloride, R(Me3Si)2SiZnCl (R = SiMe3 and Ph)

The trimethylsilyl-substituted germylzinc halides, (Me3Si) 3GeZnX (X = Cl, Br, and I), and silylzinc chlorides, R(Me3Si)2SiZnCl (R = SiMe3 and Ph) have been prepared and their molecular structures have been full determined by spectroscopic and single-crystal X-ray diffraction methods. The germylzinc halides and silylzinc chlorides have dimeric structures consisting of two μ-halogen atoms. The reactivity of germylzinc chloride with substrates is also examined.