910912-37-7

Basic information

• Product Name: tert-butyl 3-diphenylphosphinoyl-4-oxo-4-phenyl-butanoate
• Synonyms: tert-butyl 3-diphenylphosphinoyl-4-oxo-4-phenyl-butanoate
• CAS NO: 910912-37-7
• Molecular Weight: 434.472
• Mol File: 910912-37-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: tert-butyl 3-diphenylphosphinoyl-4-oxo-4-phenyl-butanoate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 3-diphenylphosphinoyl-4-oxo-4-phenyl-butanoate(910912-37-7)
• EPA Substance Registry System: tert-butyl 3-diphenylphosphinoyl-4-oxo-4-phenyl-butanoate(910912-37-7)

Safety Data

• Hazardous Substances Data: 910912-37-7(Hazardous Substances Data)

Upstream product

• 2129-89-7 diphenyl(methyl)phosphine oxide 
• 93-58-3 benzoic acid methyl ester 
• 5292-43-3 bromoacetic acid tert-butyl ester 
• 1733-58-0 phenacyldiphenylphosphine oxide 

Downstream Products

• 2051-95-8 succinylbenzene 

Relevant articles and documents

Diphenylphosphinoyl-mediated synthesis of ketones

α-Diphenylphosphinoyl ketones are selectively and sequentially alkylated at the α-position. Double lithiation and selective alkylation occurs at the less stabilised γ-position. Dephosphinoylation of the alkylation products gives ketones. Mono-alkylation is selective, highly crystalline intermediates are formed and a one-pot strategy is possible. The method is ideally suited for the preparation of acid-sensitive ketones. The Royal Society of Chemistry 2006.