91136-60-6

Basic information

• Product Name: 6-HYDROXY-4-METHYL-2-OXO-2H-CHROMENE-5-CARBALDEHYDE
• Synonyms: 6-HYDROXY-4-METHYL-2-OXO-2H-CHROMENE-5-CARBALDEHYDE
• CAS NO: 91136-60-6
• Molecular Formula: C₁₁H₈O₄
• Molecular Weight: 204.18
• Mol File: 91136-60-6.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 6-HYDROXY-4-METHYL-2-OXO-2H-CHROMENE-5-CARBALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 6-HYDROXY-4-METHYL-2-OXO-2H-CHROMENE-5-CARBALDEHYDE(91136-60-6)
• EPA Substance Registry System: 6-HYDROXY-4-METHYL-2-OXO-2H-CHROMENE-5-CARBALDEHYDE(91136-60-6)

Safety Data

• Hazardous Substances Data: 91136-60-6(Hazardous Substances Data)

Upstream product

• 2373-31-1 6-hydroxy-4-methyl-chromen-2-one 
• 100-97-0 hexamethylenetetramine 

Downstream Products

• 1233766-17-0 6-hydroxy-4-methyl-5-([1,1';4',1'']terphenyl-4-ylimino)methyl-2H-1-benzopyran-2-one 
• 1233766-14-7 6-hydroxy-4-methyl-5-(2'-methoxyphenylimino)methyl-2H-1-benzopyran-2-one 
• 1233766-09-0 6-hydroxy-4-methyl-5-(4'-methylphenylimino)methyl-2H-1-benzopyran-2-one 
• 1233766-13-6 6-hydroxy-4-methyl-5-(4'-methoxyphenylimino)methyl-2H-1-benzopyran-2-one 
• 1233766-12-5 6-hydroxy-5-((2'-hydroxyphenylimino)methyl)-4-methyl-2H-1-benzopyran-2-one 
• 1233766-11-4 6-hydroxy-4-methyl-5-(3'-methylphenylimino)methyl-2H-1-benzopyran-2-one 
• 1233766-10-3 6-hydroxy-4-methyl-5-(2'-methylphenylimino)methyl-2H-1-benzopyran-2-one 
• 1233766-15-8 6-hydroxy-4-methyl-5-(2'-phenylaminophenylimino)methyl-2H-1-benzopyran-2-one 
• 93327-45-8 5-[(2,4-dinitro-phenylhydrazono)-methyl]-6-hydroxy-4-methyl-coumarin 

Relevant articles and documents

Solvent-induced E/Z(C=N)-isomerization of imines of some hydroxy-substituted formylcoumarins

Aromatic imines, namely, 5-formyl-6-hydroxy-4-methyl- and 8-formyl-7-hydroxy-4-methylcoumarin derivatives, have been synthesized. A dependence of their spectral characteristics (1H NMR spectra, electronic absorption spectra) from the solvent (DMSO, CHCl3, DMF, acetonitrile, MeOH) has been studied. The solvatochromic effects observed for a number of imines, first of all, for 7-hydroxy-4-methyl-8-(4'-nitrophenylimino) methyl-2H-1-benzopyran-2-one, were related to their E/Z-isomerization with respect to the C=N bond based on the quantum chemical calculations by the AM1, PM3, PPP CI methods.