91145-94-7

Basic information

• Product Name: Cyclopropanecarbonitrile, 2,2-bis(phenylthio)-
• CAS NO: 91145-94-7
• Molecular Formula: C16H13NS2
• Molecular Weight: 283.418
• Mol File: 91145-94-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cyclopropanecarbonitrile, 2,2-bis(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanecarbonitrile, 2,2-bis(phenylthio)-(91145-94-7)
• EPA Substance Registry System: Cyclopropanecarbonitrile, 2,2-bis(phenylthio)-(91145-94-7)

Safety Data

• Hazardous Substances Data: 91145-94-7(Hazardous Substances Data)

Upstream product

• 3712-82-1 2,2-dichlorocyclopropanecarbonitrile 
• 108-98-5 thiophenol 
• 930-69-8 sodium thiophenolate 

Relevant articles and documents

Phase-transfer catalysed (PTC) reactions of 1,1-dichloro-2-cyanocyclopropane with nucleophiles. Identification of intermediates

An addition-elimination mechanism for PTC reactions of phenols with 1,1-dichloro-2-cyanocyclopropane (1) is supported by trapping of intermediate cyclopropenes 3 and 5. PTC reactions of 1 with a series of phenols 2a-d, thiophenol (2e), alcohols 2f,g and dithioles 11a,b led to formation of disubstituted cyanocyclopropanes 6a-d, 6e, 6f,g or spiroproducts 12a,b, respectively. Under acidic conditions or thermally, dialkoxycyclopropanes 6f,g or spirane 12a were transformed into alkyl 3-cyanopropionates 10f,g and ketene dithioacetal 13a.