91288-16-3

Basic information

• Product Name: methyl (4R,5R)-5-(1,3-O-benzylidene-D-erythro-glycerol-1-yl)-4-(ethoxycarbonyl)-2-(methoxycarbonyl)oxazolidin-2-yl acetate
• Synonyms: methyl (4R,5R)-5-(1,3-O-benzylidene-D-erythro-glycerol-1-yl)-4-(ethoxycarbonyl)-2-(methoxycarbonyl)oxazolidin-2-yl acetate
• CAS NO: 91288-16-3
• Molecular Weight: 453.446
• Mol File: 91288-16-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl (4R,5R)-5-(1,3-O-benzylidene-D-erythro-glycerol-1-yl)-4-(ethoxycarbonyl)-2-(methoxycarbonyl)oxazolidin-2-yl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl (4R,5R)-5-(1,3-O-benzylidene-D-erythro-glycerol-1-yl)-4-(ethoxycarbonyl)-2-(methoxycarbonyl)oxazolidin-2-yl acetate(91288-16-3)
• EPA Substance Registry System: methyl (4R,5R)-5-(1,3-O-benzylidene-D-erythro-glycerol-1-yl)-4-(ethoxycarbonyl)-2-(methoxycarbonyl)oxazolidin-2-yl acetate(91288-16-3)

Safety Data

• Hazardous Substances Data: 91288-16-3(Hazardous Substances Data)

Upstream product

• 83078-98-2 ethyl 2-amino-4,6-O-benzylidene-2-deoxy-D-gluconate 
• 762-42-5 dimethyl acetylenedicarboxylate 

Downstream Products

• 3646-68-2 D-glucosaminic acid 
• 25007-54-9 Dimethyl 2-oxosuccinate 
• 100-52-7 benzaldehyde 
• 91288-19-6 ethyl 3,5-di-O-acetyl-4,6-O-benzylidene-2-deoxy-2-<(Z)-(1,2-dimethoxycarbonylvinyl)amino>-D-gluconate 
• 91288-18-5 methyl (4R,5R)-5-(2-O-acetyl-1,3-O-benzylidene-D-erythro-glycerol-1-yl)-4-(ethoxycarbonyl)-2-(methoxycarbonyl)oxazolidin-2-yl acetate 

Relevant articles and documents

REACTION OF ETHYL 2-AMINO-4,6-O-BENZYLIDENE-2-DEOXY-D-GLUCONATE WITH ACETYLENIC ESTERS

Ethyl 2-amino-4,6-O-benzylidene-2-deoxy-D-gluconate adds to acetylenic esters to give sugar enaminones.The following acetylene derivatives have been employed: methyl propiolate, ethyl phenylpropiolate, and dimethyl acetylenedicarboxylate (6).With compound 6, the reaction leads to a mixture of the expected enaminone and the isomeric oxazolidine derivative.The structures and configurations of the new compounds were studied by spectroscopic and chemical methods.