91292-08-9

Basic information

• Product Name: 5,5,8aβ-trimethyl-2-(3-oxo-2-phenylthiobutyl)-4aα-perhydronaphthalen-1-one
• Synonyms: 5,5,8aβ-trimethyl-2-(3-oxo-2-phenylthiobutyl)-4aα-perhydronaphthalen-1-one
• CAS NO: 91292-08-9
• Molecular Weight: 372.572
• Mol File: 91292-08-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 5,5,8aβ-trimethyl-2-(3-oxo-2-phenylthiobutyl)-4aα-perhydronaphthalen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5,5,8aβ-trimethyl-2-(3-oxo-2-phenylthiobutyl)-4aα-perhydronaphthalen-1-one(91292-08-9)
• EPA Substance Registry System: 5,5,8aβ-trimethyl-2-(3-oxo-2-phenylthiobutyl)-4aα-perhydronaphthalen-1-one(91292-08-9)

Safety Data

• Hazardous Substances Data: 91292-08-9(Hazardous Substances Data)

Upstream product

• 13522-48-0 3-(phenylthio)-but-3-en-2-one 
• 60134-39-6 (-)-(4aS,8aS)-3,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalen-1(2H)-one 

Downstream Products

• 514-62-5 ferruginol 
• 91292-07-8 1,1,4aβ-trimethyl-7-phenylthio-1,2,3,4,4a,8,8a,9,10,10a-decahydro-10aα-phenanthren-6(7H)-one 

Relevant articles and documents

Reactions of 3-Phenylthiobut-3-en-2-one. Part 4. Novel and Efficient Synthesis of 7-hydroxycalamenene, Ferruginol, and D-Homoestrone

The annelation reaction of 3-phenylthiobut-3-en-2-one with carvomenthone (1) gives 8a-hydroxy-4α-isopropyl-1-methyl-6-phenylthioperhydronaphthalen-7-one (2), which is converted into 7-hydroxycalamenene (4) by subsequent dehydration, methylation, and aroma