91347-87-4

Basic information

• Product Name: Benzene, (1-cyclobuten-1-ylmethyl)-
• CAS NO: 91347-87-4
• Molecular Formula: C11H12
• Molecular Weight: 144.216
• Mol File: 91347-87-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, (1-cyclobuten-1-ylmethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (1-cyclobuten-1-ylmethyl)-(91347-87-4)
• EPA Substance Registry System: Benzene, (1-cyclobuten-1-ylmethyl)-(91347-87-4)

Safety Data

• Hazardous Substances Data: 91347-87-4(Hazardous Substances Data)

Upstream product

• 498-66-8 norborn-2-ene 
• 591-50-4 iodobenzene 
• 593-60-2 Vinyl bromide 
• 141694-63-5 (E)-1-iodo-3-phenyl-1-propene 

Relevant articles and documents

Zirconium-Mediated Cross-Coupling of Terminal Alkynes and Vinyl Bromides: Selective Synthesis of Cyclobutene and 1,3-Diene Derivatives

A diastereoselective synthesis of 1,3-butadiene or cyclobutene derivatives by a zirconium-mediated reaction of alkenyllithium compounds and vinyl bromides is reported. The key steps involve the generation of zirconocene-alkyne complexes from haloalkenes and subsequent coupling with alkenyl bromides. Thus, formally the process supposes the cross-coupling reaction between a terminal alkyne and an alkenyl bromide. Moreover, the use of butyl vinyl ether instead of vinyl bromide as the unsaturated system allows an alternative access to different 1,3-butadiene regioisomers.