91459-39-1

Basic information

• Product Name: 1H-Indole, 1-methyl-5-(2-phenylethenyl)-, (E)-
• CAS NO: 91459-39-1
• Molecular Formula: C17H15N
• Molecular Weight: 233.313
• Mol File: 91459-39-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1H-Indole, 1-methyl-5-(2-phenylethenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Indole, 1-methyl-5-(2-phenylethenyl)-, (E)-(91459-39-1)
• EPA Substance Registry System: 1H-Indole, 1-methyl-5-(2-phenylethenyl)-, (E)-(91459-39-1)

Safety Data

• Hazardous Substances Data: 91459-39-1(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 1169516-59-9 1-methyl-5-(2-phenylethynyl)-1H-indole 
• 29906-67-0 1-methyl-5-nitro-1H-indole 
• 10075-52-2 5-bromo-1-methyl-H-indole 
• 100-44-7 benzyl chloride 
• 60082-02-2 1-methylindoline-5-carboxaldehyde 
• 91459-37-9 1-Methyl-5-(trans-2-phenyl-1-ethenyl)indoline 

Downstream Products

• 90923-75-4 1-methyl-1H-indole-5-carboxaldehyde 

Relevant articles and documents

Pd-Catalyzed Cross-Coupling of Organostibines with Styrenes to Give Unsymmetric (E)-Stilbenes and (1 E,3 E)-1,4-Diarylbuta-1,3-dienes and Fluorescence Properties of the Products

A general and effective palladium-catalyzed cross-coupling of organostibines with styrenes to give (E)-olefins was disclosed. By the use of an organostibine reagent, this method can produce unsymmetric (E)-1,2-diarylethylenes and (1E,3E)-1,4-diarylbuta-1,3-dienes in good yields with high E/Z selectivity and good functional group tolerance. Resveratrol and DMU-212 were synthesized in high yield. The protocol can be extended to the synthesis of (1E,3E,5E)-1,6-diphenylhexa-1,3,5-triene in 40% yield. Products 5e, 5f, and 7a showed good photoluminescence quantum yields ranging from 72 to 99%.

Palladium-Catalyzed Mizoroki-Heck Reaction of Nitroarenes and Styrene Derivatives

We have developed a Mizoroki-Heck reaction of nitroarenes with alkenes under palladium catalysis. The use of a Pd/BrettPhos catalyst promoted the alkenylation, whereas other catalysts led to a decrease in the product yield. In addition to nitroarenes, nitroheteroarenes were also applicable to the present reaction. The combination of a nucleophilic aromatic substitution (SNAr) with the denitrative alkenylation produced a multifunctionalized arene in a one-pot operation.

INDOLE DERIVATIVES. 124. 5-(2-PHENYLETHENYL)INDOLINES AND 5-(2-PHENYLETHENYL)INDOLES

5-(2-Phenylethenyl)indolines, the dehydrogenation of wich leads to the formation of the corresponding compounds of the indole series, were obtained from 5-formyl-1-methyl(or benzyl)indolines via the Grignard reaction with benzylmagnesium chloride and subs