91509-10-3Relevant articles and documents
REACTIONS OF N-CHLOROAMINES WITH OLEFINS IN THE PRESENCE OF SULFURE TRIOXIDE
Zefirov, N. S.,Zyk, N. V.,Kolbasenko, S. I.,Kutateladze, A. G.
, p. 887 - 888 (1984)
-
Sulfur Trioxide Assisted Electrophilic Addition of R2NCl to Olefins
Zefirov, Nikolai S.,Zyk, Nikolai V.,Kolbasenko, Sergei I.,Kutateladze, Andrey G.
, p. 4539 - 4543 (2007/10/02)
The one-pot reaction of SO3, N,N-dialkylchloroamines, and olefins gives N,N-dialkylsulfamates of the corresponding chlorohydrins (6).These additions are shown to have electrophilic character.Experimental evidence supports the principle that SO3 increases