915939-64-9

Basic information

• Product Name: Carbonic acid, 1,1-dimethylethyl (2E)-3-(3-fluorophenyl)-2-propen-1-yl ester
• CAS NO: 915939-64-9
• Molecular Formula: C14H17FO3
• Molecular Weight: 252.286
• Mol File: 915939-64-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Carbonic acid, 1,1-dimethylethyl (2E)-3-(3-fluorophenyl)-2-propen-1-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbonic acid, 1,1-dimethylethyl (2E)-3-(3-fluorophenyl)-2-propen-1-yl ester(915939-64-9)
• EPA Substance Registry System: Carbonic acid, 1,1-dimethylethyl (2E)-3-(3-fluorophenyl)-2-propen-1-yl ester(915939-64-9)

Safety Data

• Hazardous Substances Data: 915939-64-9(Hazardous Substances Data)

Upstream product

• 1121-86-4 1-Fluoro-3-iodobenzene 
• 456-48-4 3-Fluorobenzaldehyde 
• 24424-99-5 di-tert-butyl dicarbonate 
• 26905-44-2 3-(3-fluorophenyl)-2-propen-1-ol 
• 351-46-2 ethyl 3-(3-fluorophenyl)acrylate 

Downstream Products

• 915939-73-0 (S)-1-(3'-fluorophenyl)prop-2-en-1-ol 

Relevant articles and documents

Stereodivergent allylic substitutions with aryl acetic acid esters by synergistic iridium and lewis base catalysis

The preparation of all possible stereoisomers of a given chiral molecule bearing multiple stereocenters by a simple and unified method is a significant challenge in asymmetric catalysis. We report stereodivergent allylic substitutions with aryl acetic acid esters catalyzed synergistically by a metallacyclic iridium complex and benzotetramisole. Through permutations of the enantiomers of the two chiral catalysts, all four stereoisomers of the products bearing two adjacent stereocenters are accessible with high diastereoselectivity and enantioselectivity. The resulting chiral activated ester products can be converted readily to enantioenriched amides, unactivated esters, and carboxylic acids in a onepot manner.