917612-30-7

Basic information

• Product Name: 6-Nonen-2-one, 6-methyl-9-phenyl-, (6E)-
• CAS NO: 917612-30-7
• Molecular Formula: C16H22O
• Molecular Weight: 230.35
• Mol File: 917612-30-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 6-Nonen-2-one, 6-methyl-9-phenyl-, (6E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 6-Nonen-2-one, 6-methyl-9-phenyl-, (6E)-(917612-30-7)
• EPA Substance Registry System: 6-Nonen-2-one, 6-methyl-9-phenyl-, (6E)-(917612-30-7)

Safety Data

• Hazardous Substances Data: 917612-30-7(Hazardous Substances Data)

Upstream product

• 187336-21-6 (E)-6-(tert-butyldiphenylsilyloxy)-3-methylhex-2-enyl acetate 
• 187336-22-7 (E)-6-(tert-butyldiphenylsilyloxy)-3-methylhex-2-en-1-ol 
• 162085-16-7 (E)-4-methyl-7-phenyl-heptan-4-ene-1-ol mesylate 
• 162085-15-6 (E)-4-methyl-7-phenyl-heptan-4-ene-1-ol 
• 100045-79-2 <(2E)-6-Hydroxy-3-methyl-2-hexenyl>acetat 
• 35334-60-2 (E)-6-acetoxy-4-methyl-4-hexenal 
• 105-87-3 3,7-dimethyl-2E,6-octadien-1-yl acetate 
• 37715-31-4 (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enyl acetate 
• 917611-89-3 (E)-6-(tert-butyldiphenylsilyloxy)-3-methylhex-2-enyl diethyl phosphate 
• 917612-13-6 (E)-5-methyl-8-phenyloct-5-enenitrile 
• 917-54-4 methyllithium 

Relevant articles and documents

Catalytic diastereoselective polycyclization of homo(polyprenyl)arene analogues bearing terminal siloxyvinyl groups

Highly diastereoselective polycyclization of homo(polyprenyl)arene analogues bearing terminal siloxyvinyl groups was catalyzed by tin(IV) chloride (10 mol %). The cyclizations of tert-butyldiphenylsilyl and triisopropylsilyl polyenol ethers gave 4α(equatorial)- and 4β(axial)-siloxypolycycles as major isomers, respectively. The strong nucleophilicity of pro-C(9), a (6E) geometry, and a bulky silyl group effectively favored the 4α-preference, whereas the weak nucleophilicity of pro-C(9), a (6Z)-geometry, and less steric hindrance of a silyl group favored the 4β-preference.