91766-77-7

Basic information

• Product Name: (4-bromophenyl)(cyclohexyl)sulfane
• Synonyms: (4-bromophenyl)(cyclohexyl)sulfane
• CAS NO: 91766-77-7
• Molecular Weight: 271.221
• Mol File: 91766-77-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (4-bromophenyl)(cyclohexyl)sulfane(CAS DataBase Reference)
• NIST Chemistry Reference: (4-bromophenyl)(cyclohexyl)sulfane(91766-77-7)
• EPA Substance Registry System: (4-bromophenyl)(cyclohexyl)sulfane(91766-77-7)

Safety Data

• Hazardous Substances Data: 91766-77-7(Hazardous Substances Data)

Upstream product

• 98-89-5 Cyclohexanecarboxylic acid 
• 106-53-6 para-bromobenzenethiol 
• 126812-30-4 1,3-dioxoisoindolin-2-yl cyclohexanecarboxylate 
• 110-82-7 cyclohexane 
• 2297-64-5 p-bromophenylsulfonyl hydrazide 
• 5335-84-2 bis(4-bromophenyl)disulfide 
• 108-86-1 bromobenzene 
• 1564-39-2 1-oxa-4-thiaspiro-<4,5>decan-2-one 

Relevant articles and documents

Visible-Light-Mediated Alkylation of Thiophenols via Electron Donor-Acceptor Complexes Formed between Two Reactants

A metal-free, photocatalyst-free, photochemical system was developed for the direct alkylation of thiophenols via electron donor-acceptor (EDA) complexes (KEDA = 145 M-1) between two reactants, N-hydroxyphthalimide esters as acceptors and thiophenol anions as donors, in the presence of a tertiary amine. The EDA complexes in the reaction system have a broad range of visible-light absorption (400-650 nm) and can trigger the reaction effectively under sunlight.

Palladium-catalyzed thiolation of alkanes and ethers with arylsulfonyl hydrazides

A new method for the preparation of alkyl aryl sulfides through direct oxidative thiolation of alkanes or ethers with arylsulfonyl hydrazides using di-tert-butyl peroxide (DTBP) as an oxidant catalyzed by Pd(OAc)2 has been reported. The C-H bonds in various alkanes or ethers were successfully converted into C-S bonds to yield the corresponding sulfides in moderate to good yields. the Partner Organisations 2014.

NONCONVENTIONAL FRIEDEL-CRAFTS CHEMISTRY III. ON THE REGIOSPECIFIC SYNTHESIS OF SPIRO-4'-ONE DERIVATIVES

The rection of 1-oxa-4-thiaspirononan-2-one (4) and/or 1-oxa-4-thiaspirodecan-2-one (5) with arenes (6) under the catalytic action of aluminum chloride afforded in all cases spiro-4'-ones (7a - g and 8a - g), -acetic acid, (9a - g and 10a - g), cycloalkylthioacetic acids, (11 and 20) aryl cycloalkyl sulfides, (14 and 23) diarylsulfides (15), diaryl disulfides and dicycloalkyl disulfides (13 and 22).The mechanisms of these reactions are discussed.Key words: Spiroisothiochroman-4-ones; Friedel-Crafts reactions.