91850-99-6

Basic information

• Product Name: Ethanone, 1-phenyl-2-[(1-phenylethyl)imino]-
• CAS NO: 91850-99-6
• Molecular Formula: C16H15NO
• Molecular Weight: 237.301
• Mol File: 91850-99-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-phenyl-2-[(1-phenylethyl)imino]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-phenyl-2-[(1-phenylethyl)imino]-(91850-99-6)
• EPA Substance Registry System: Ethanone, 1-phenyl-2-[(1-phenylethyl)imino]-(91850-99-6)

Safety Data

• Hazardous Substances Data: 91850-99-6(Hazardous Substances Data)

Upstream product

• 1075-06-5 2,2-dihydroxy-1-phenyl-ethanone 
• 618-36-0 rac-methylbenzylamine 
• 1074-12-0 phenylglyoxal hydrate 

Downstream Products

• 109387-99-7 (3S,4S)-4-Benzoyl-1-(1-phenyl-ethyl)-3-vinyl-azetidin-2-one 
• 101286-56-0 N-(α-phenylethyl)-1-phenyl-2-aminoethanol 

Relevant articles and documents

The Reaction of Phenylglyoxal with Primary Aliphatic and Aromatic Amines. Synthesis of Phenylglyoxal Monoimines and some Derivatives.

Condensation of phenylglyoxal with primary aliphatic amines yields the related keto-aldimines.When primary aromatic amines are used, aldimines, amino-hydroxy-ketones, diamino-ketones, and alkoxy-amino-ketones are obtained depending upon the nature of the amine and the experimental conditions.Alternatively the monoimines can be obtained by dehydration of C-hydroxyphenacylarylamines and by demethanolation of C-methoxyphenacylarylamines both on treatment with Pd/C catalyst.Reduction of phenylglyoxal monoimines with sodium borohydride yielded H-substituted 1-phenyl-2-aminoethanols and 1,3-dipolar cycloaddition of the imines with p-chlorobenzonitrile oxide afforded 4-substituted 5-benzoyl-3-(p-chlorophenyl)-4,5-dihydro-1,2,4-oxadiazoles.