91949-73-4Relevant articles and documents
Photochemical Synthesis of Decipiene Diterpenes
Dauben, William G.,Shapiro, Gideon
, p. 4252 - 4258 (2007/10/02)
The decipiene diterpene nucleus has been synthesized by an intramolecular photocycloaddition between an enone and an allene grouping.The process makes use, for the first time, of a stereocontrol element at a remote center in the precursor unit to control the final stereochemistry of the product.A formal total synthesis of (+/-)-trihydroxydecipiadiene has been achieved.