91970-30-8

Basic information

• Product Name: (2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol
• CAS NO: 91970-30-8
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.2277
• Mol File: 91970-30-8.mol
• Article Data: 9

Chemical Properties

• Boiling Point: 320.9°C at 760 mmHg
• Flash Point: 144.2°C
• Density: 1.059g/cm³
• Vapor Pressure: 0.000128mmHg at 25°C
• Refractive Index: 1.565
• CAS DataBase Reference: (2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol(91970-30-8)
• EPA Substance Registry System: (2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol(91970-30-8)

Safety Data

• Hazardous Substances Data: 91970-30-8(Hazardous Substances Data)

Usage

Description

(2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol, commonly known as p-anisyl isobutyrylcarbinol, is a chemical compound that belongs to the class of alcohols. It has a molecular formula of C11H14O2 and a molecular weight of 178.23 g/mol. This colorless to pale yellow liquid possesses a sweet, floral odor.

Uses

Used in Fragrance Industry:
(2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol is used as a fragrance ingredient for its sweet, floral scent in various consumer products such as perfumes, cosmetics, and personal care products.
Used in Pharmaceutical Industry:
(2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol is used as a chemical intermediate in the synthesis of pharmaceuticals, contributing to the development of new medications and therapeutic agents.
Used in Organic Synthesis:
(2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol is utilized as a building block in the synthesis of other organic compounds, expanding its applications across different chemical and industrial processes.
(2Z)-3-(4-methoxyphenyl)-2-methylprop-2-en-1-ol is considered to have low toxicity and is generally considered safe for use in the intended applications.

Upstream product

• 75101-99-4 (E)-3-(4-methoxyphenyl)-2-methylacrylaldehyde 
• 123-11-5 4-methoxy-benzaldehyde 
• 50-00-0 formaldehyd 
• 2749-94-2 1-methoxy-4-(prop-1-yn-1-yl)benzene 
• 17226-85-6 α,β-syn-methyl 3-hydroxy-2-methyl-3-(p-methoxyphenyl)propionate 
• 126356-04-5 (E)-methyl 2-methyl-3-(p-methoxyphenyl)prop-2-enoate 
• 52750-05-7 ethyl (E)-3-(4-methoxyphenyl)-2-methylpropenoate 

Downstream Products

• 37542-93-1 Di-(E-α-methyl-p-methoxycinnamyl)-ether 
• 103305-41-5 (2R,3S)-2-Ethyl-3-(4-methoxy-phenyl)-4-methyl-pent-4-enoic acid methyl ester 
• 103305-41-5 (2S,3S)-2-Ethyl-3-(4-methoxy-phenyl)-4-methyl-pent-4-enoic acid methyl ester 
• 115753-99-6 2-methyl-3(4'-methoxy-1'-phenyl)allyl bromide 
• 103305-40-4 (2S,3S)-3-(4-Methoxy-phenyl)-2,4-dimethyl-pent-4-enoic acid ethyl ester 
• 103305-40-4 (2R,3S)-3-(4-Methoxy-phenyl)-2,4-dimethyl-pent-4-enoic acid ethyl ester 
• 92656-06-9 (2R,3R)-(1,3)-diacetoxy-2-methyl-3-p-methoxyphenylpropane 
• 185681-32-7 (S)-1-bromo-2-methyl-3-(p-methoxyphenyl)propanol 
• 79253-39-7 (S)-(-)-3-(4-methoxyphenyl)-2-methylpropan-1-ol 
• 185681-33-8 (2S)-2-methyl-3-(p-methoxyphenyl)-1-phenylsulfonylpropane 
• 262849-39-8 (2S)-1-acetoxy-2-methyl-3-p-methoxyphenylpropane 
• 262849-41-2 Acetic acid (2R,3R)-3-hydroxy-3-(4-methoxy-phenyl)-2-methyl-propyl ester 

Relevant articles and documents

Complex Polyheterocycles and the Stereochemical Reassignment of Pileamartine A via Aza-Heck Triggered Aryl C-H Functionalization Cascades

Structurally complex benzo- and spiro-fused N-polyheterocycles can be accessed via intramolecular Pd(0)-catalyzed alkene 1,2-aminoarylation reactions. The method uses N-(pentafluorobenzoyloxy)carbamates as the initiating motif, and this allows aza-Heck-type alkene amino-palladation in advance of C-H palladation of the aromatic component. The chemistry is showcased in the first total synthesis of the complex alkaloid (+)-pileamartine A, which has resulted in the reassignment of its absolute stereochemistry.

Highly enantioselective hydrogenation of 2-substituted-2-alkenols catalysed by a ChenPhos-Rh complex

Highly enantioselective hydrogenation of a variety of 2-substituted-2- alkenols has been achieved using a ChenPhos-Rh complex as catalyst, giving ≥99% ee for most substrates. Optically active antifungal agent amorolfine was first synthesised using hydrogenation as the key step. This journal is

An organocatalytic asymmetric nazarov cyclization

An organocatalytic asymmetric Nazarov cyclization of diketoesters that proceeds by means of a dual activation mechanism has been developed. Screening of a number of catalysts led to a new thiourea that incorporates a primary amino group. The method gives rise to cyclic products with two adjacent quaternary asymmetric carbon atoms, one of which is an all-carbon stereocenter, with complete or nearly complete diastereoselectivity and in high or very high enantiomeric excess. A brief and very convenient synthesis of the acyclic diketoester starting materials through nucleophilic addition to a ketene is also described.