92013-12-2

Basic information

• Product Name: 2-BUTYL-1H-INDENE
• Synonyms: 2-BUTYL-1H-INDENE;2-Butylindene
• CAS NO: 92013-12-2
• Molecular Formula: C₁₃H₁₆
• Molecular Weight: 172.27
• Product Categories: Indanone & Indene
• Mol File: 92013-12-2.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 262℃
• Flash Point: 108℃
• Appearance: transparent to yellow liquid
• Density: 0.954
• Vapor Pressure: 0.018mmHg at 25°C
• Refractive Index: 1.54
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• CAS DataBase Reference: 2-BUTYL-1H-INDENE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BUTYL-1H-INDENE(92013-12-2)
• EPA Substance Registry System: 2-BUTYL-1H-INDENE(92013-12-2)

Safety Data

• Hazardous Substances Data: 92013-12-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H16/c1-2-3-6-11-9-12-7-4-5-8-13(12)10-11/h4-5,7-9H,2-3,6,10H2,1H3

Upstream product

• 693-02-7 hex-1-yne 
• 307496-27-1 2-bromobenzylzinc(II) bromide 
• 109-65-9 1-bromo-butane 
• 7664-93-9 sulfuric acid 
• 615-13-4 2-indanone 
• 10485-09-3 2-bromoindene 

Downstream Products

• 165688-66-4 bis(2-n-butylindenyl)zirconium dichloride 
• 165688-66-4 (CH₃(CH₂)3C₉H₆)2ZrCl₂ 
• 361212-05-7 C₉H₆(CH₂)2C₆H₅ZrCl₂C₉H₆(CH₂)3CH₃ 
• 361211-97-4 C₉H₆(CH₂)C₆H₅ZrCl₂C₉H₆(CH₂)3CH₃ 
• 66324-75-2 2-n-butylindan 
• 926925-75-9 4,7-dihydro-2-butylindane 

Relevant articles and documents

Nickel-catalyzed carboannulation reaction of o-bromobenzyl zinc bromide with unsaturated compounds

(Chemical Equation Presented) A number of indenes have been prepared in good yields by treating o-bromobenzyl zinc bromide 1 with various terminal and internal alkynes in the presence of a nickel catalyst. The nickel-catalyzed carboannulation reaction was successfully extended to the synthesis of indane derivatives by reaction of 1 with acrylates and styrene.

Synthesis and characterization of new bis(2-R-indenyl) zirconium dichloride complexes for the olefin polymerization

A series of 2-alkylindene(2-RInd; R=Me, i-Pr, n-Bu, Bzl, Cy, t-Bu) were prepared by nucleophilic addition of the corresponding alkyl anions to 2-indanone in the presence (or absence) of LaCl3. With these 2-alkylindenes, bis(2-alkylindenyl)zirconium dichloride complexes were synthesized to investigate the effects of alkyl substituents at 2-position of indene on the rotational conversion rate between rotamers (racemic and meso) and the catalytic activities toward olefin polymerization. Analysis of NMR spectra could line up the electron donating abilities and steric bulkiness of alkyl substituents in order and variable temperature NMR analysis (from 298 to 193 K) proved that these alkyls could not freeze free rotation of indenyl ligands. These complexes showed catalytic activities toward ethylene and propylene polymerization and the variation of catalytic activities(PE, Me〉Cy〉i-Pr〉Bzl〉n-Bu; PP, Me〉n-Bu〉i-Pr〉Cy〉Bzl), molecular weights(PE, n-Bu〉Cy〉i-Pr〉Me〉Bzl; PP, n-Bu〉Me〉Cy〉i-Pr〉Bzl), and polydispersities(PE, 2.80-5.05; PP, 2.23-3.30) were rationalized with steric, electronic, and structural factors. Steric bulkiness of substituents played an important role in the propylene polymerization but relative importance of these factors were different in the ethylene polymerization.

Synthesis of Biological Markers in Fossil Fuels. 2. Synthesis and 13C NMR Studies of Substituted Indans and Tetralins

Unambiguous syntheses of all possible methyl, ethyl, n-propyl, and n-butyl derivatives of indan and tetralin were developed using the Kumada coupling procedure involving the reaction of aryl or vinyl halides with Grignard reagents in the presence of nickel(II) chloride.An analysis of the 13C NMR spectra of these compounds was also completed.