92040-43-2

Basic information

• Product Name: phenyl azepane-1-carboxylate
• Synonyms: phenyl azepane-1-carboxylate
• CAS NO: 92040-43-2
• Molecular Weight: 219.283
• Mol File: 92040-43-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: phenyl azepane-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: phenyl azepane-1-carboxylate(92040-43-2)
• EPA Substance Registry System: phenyl azepane-1-carboxylate(92040-43-2)

Safety Data

• Hazardous Substances Data: 92040-43-2(Hazardous Substances Data)

Upstream product

• 111-49-9 hexamethylene imine 
• 124-38-9 carbon dioxide 
• 98-80-6 phenylboronic acid 
• 102-09-0 bis(phenyl) carbonate 

Relevant articles and documents

A copper-catalyzed oxidative coupling reaction of arylboronic acids, amines and carbon dioxide using molecular oxygen as the oxidant

A Cu-catalyzed oxidative coupling reaction of arylboronic acids, amines and carbon dioxide is described for the first time in this paper. The reaction tolerates a wide range of functional groups, providing a convenient protocol for the synthesis of various O-aryl carbamates. The successful development of the transformation was enabled by the use of BF3·OEt2 as the promoter and molecular oxygen as the oxidant. Mechanistic studies suggested that the CuII carbamato complex is involved in the catalytic transformation.