92144-07-5

Basic information

• Product Name: 3,6-Pyridazinedicarboxylic acid, 4-methoxy-, dimethyl ester
• CAS NO: 92144-07-5
• Molecular Formula: C9H10N2O5
• Molecular Weight: 226.189
• Mol File: 92144-07-5.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 3,6-Pyridazinedicarboxylic acid, 4-methoxy-, dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 3,6-Pyridazinedicarboxylic acid, 4-methoxy-, dimethyl ester(92144-07-5)
• EPA Substance Registry System: 3,6-Pyridazinedicarboxylic acid, 4-methoxy-, dimethyl ester(92144-07-5)

Safety Data

• Hazardous Substances Data: 92144-07-5(Hazardous Substances Data)

Upstream product

• 922-69-0 1,1-dimethoxyethylene 
• 2166-14-5 1,2,4,5-tetrazine-3,6-dicarboxylic acid dimethyl ester 

Relevant articles and documents

TOTAL SYNTHESIS OF PRODIGIOSIN

The total synthesis of prodigiosin (1), possessing the characteristic pyrrolylpyrromethene skeleton of a class of naturally-occuring polypyrroles, is detailed.The approach is based on the application of an inverse electron demand Diels-Alder reaction of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate in a 1,2,4,5-tetrazine -> 1,2-diazine -> pyrrole strategy for preparation of prodigiosin pyrrole ring B and the subsequent implementation of an intramolecular palladium(II)-promoted 2,2'-diaryl (2,2'-bipyrrole) coupling for construction of the prodigiosin 2,2'-bipyrrole AB ring system.

Silyl enol ethers as 2π components in (4+2) cycloadditions: Preparative and kinetic results

Easily accessible open chain and cyclic silyl enolethers show dienophilic reactivity in (4+2)-cycloaddition reactions with inverse electron demand equivalent to enol ethers. Preparative and kinetic results are reported.

Thermal Cycloaddition of Dimethyl 1,2,4,5-Tetrazine-3,6-dicarboxylate with Electron-Rich Olefins: 1,2-Diazine and Pyrrole Introduction. Preparation of Octamethylporphin (OMP)

An investigation of the inverse electron demand Diels-Alder reactions of dimethyl 1,2,4,5-tetrazine-3,6-dicarboxylate with electron-rich olefins for the introduction of 1,2-diazines and pyrroles is described.A short synthesis of 2,3,7,8,12,13,17,18-octamethylporphin (OMP) is detailed.