92157-35-2Relevant articles and documents
Cage Like Al-KIT-5 Mesoporous Materials for C-C Bond Formation Reactions under Solvent Free Conditions
Baruah, Pranjal K.,Dutta, Prantu,Kalita, Pranjal
, p. 2037 - 2045 (2015/12/24)
The C-C bond forming reactions are of fundamental importance in chemistry. As a result there is ever growing interest for chemists to develop new methods for C-C bond formation. We report here three dimensional nano-cage mesoporous aluminosilicate materia
Mukaiyama aldol reaction of trimethylsilyl enolate with aldehyde catalyzed by CuI
Kalita, Hima Rani,Borah, Arun Jyoti,Phukan, Prodeep
, p. 289 - 292 (2013/05/22)
Cuprous iodide has been found to be a very effective catalyst for Mukaiyama aldol reaction of trimethylsilyl ketene acetal with aldehydes. The new catalytic system promotes efficiently the Mukaiyama aldol reaction in DMF to produce corresponding β-hydroxy carbonyl compounds in high yield.
Catalysis of Mukaiyama aldol reactions by a tricyclic aluminum alkoxide Lewis acid
Raders, Steven M.,Verkade, John G.
supporting information; experimental part, p. 5417 - 5428 (2009/12/08)
(Chemical Equation Presented) The Mukayiama aldol reaction of aldehydes is efficiently accomplished with a low concentration of the dimeric alumatrane catalyst 2 at mild or subambient temperatures. Our protocol tolerates a wide variety of electron-rich, neutral, and deficient aryl, alkyl, and heterocyclic aldehydes. A wide variety of enol silyl ethers are also tolerated. An intermediate that was isolated provides mechanistic information regarding the role of dimeric 2 in the Mukaiyama aldol reaction. Experimental evidence is presented for the stronger Lewis acidity of 5 compared with F3B.