92234-01-0

Basic information

• Product Name: 1-Propanone, 1,3-diphenyl-3-[(trimethylsilyl)oxy]-
• CAS NO: 92234-01-0
• Molecular Formula: C18H22O2Si
• Molecular Weight: 298.457
• Mol File: 92234-01-0.mol
• Article Data: 42

Chemical Properties

• CAS DataBase Reference: 1-Propanone, 1,3-diphenyl-3-[(trimethylsilyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanone, 1,3-diphenyl-3-[(trimethylsilyl)oxy]-(92234-01-0)
• EPA Substance Registry System: 1-Propanone, 1,3-diphenyl-3-[(trimethylsilyl)oxy]-(92234-01-0)

Safety Data

• Hazardous Substances Data: 92234-01-0(Hazardous Substances Data)

Upstream product

• 111061-31-5 1-phenoxy-1-trimethylsilyloxyethene 
• 100-52-7 benzaldehyde 
• 532-27-4 1-chloroacetophenone 
• 98-86-2 acetophenone 
• 150081-96-2 tris(trimethylsilyl)silyl trifluoromethanesulfonate 
• 13735-81-4 1-styrenyloxytrimethylsilane 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 69739-34-0 t-butyldimethylsiyl triflate 
• 66324-10-5 tert-butyldimethyl(1-phenylvinyloxy)silane 
• 42052-51-7 3-hydroxy-1,3-diphenylpropan-1-one 
• 1125-88-8 benzaldehyde dimethyl acetal 

Downstream Products

• 5381-86-2 (1R,3S)-1,3-diphenylpropane-1,3-diol 
• 42052-51-7 (R)-3-hydroxy-1,3-diphenylpropane-1-one 
• 88704-60-3 5-Benzoyl-trans-2,trans-4,trans-6-triphenyl-1,3-dioxane 
• 614-47-1 1,3-diphenyl-propen-3-one 
• 42052-51-7 3-hydroxy-1,3-diphenylpropan-1-one 
• 82959-04-4 5-benzoyl-2,4,6-triphenyl-1,3-dioxane 
• 52306-31-7 3-Brom-1,3-diphenyl-1-propanon 
• 32831-01-9 3-chloro-3-phenylpropiophenone 

Relevant articles and documents

1,3-Addition of silyl enol ethers to nitrones catalyzed by mesoporous aluminosilicate

Mesoporous aluminosilicate (Al-MCM-41) was found to be an effective and reusable catalyst for 1,3-addition of silyl enol ethers to nitrones. The reaction proceeded under mild reaction conditions to afford the corresponding β-(siloxyamino)ketones in high y

Mukaiyama aldol reaction catalyzed by (benz)imidazolium-based halogen bond donors

A series of cationic monodentate and bidentate iodo(benz)imidazolium-based halogen bond (XB) donors were employed as catalysts in a Mukaiyama aldol reaction. While 5 mol% of a monodentate variant showed noticeable activity, asyn-preorganized bidentate XB

Cooperative organocatalysis of Mukaiyama-type aldol reactions by thioureas and nitro compounds

A unique organocatalytic system for Mukaiyama-type aldol reactions based on the cooperative action of nitro compounds and thioureas has been identified. This system is compatible with a wide range of substrates and does not require low temperatures, inert atmospheres, or an aqueous workup. A catalytic mechanism based on nitro group-mediated silyl cation transfer has been proposed.

Chemoselective silyl transfer in the Mukaiyama aldol reaction promoted by super silyl Lewis acid

In the silyl Lewis acid-promoted Mukaiyama aldol reaction, the steric and electronic properties of the silyl group on the silyl Lewis acid influence the reaction mechanism and product distribution. When super silyl triflates such as (TMS)3SiOTf and (TES)3SiOTf are used as Lewis acids, the silyl group of the silyl enol ether chemoselectively transfers to the product. The mechanistic details have been investigated using density functional theory (DFT) calculations.