92241-60-6Relevant articles and documents
Pd-Catalyzed Coupling of N-Tosylhydrazones with Benzylic Phosphates: Toward the Synthesis of Di- or Tri-Substituted Alkenes
Zhang, Kena,Provot, Olivier,Alami, Mouad,Tran, Christine,Hamze, Abdallah
, p. 1249 - 1261 (2022/02/07)
This study shows that various di- and tri-substituted alkenes with high chemoselectivity were obtained in good to high yields by coupling N-tosylhydrazones (NTHs) with benzylic phosphates as electrophilic partners. The obtained new catalytic system consis
Rapid construction of multisubstituted olefin structures using vinylboronate ester platform leading to highly fluorescent materials
Itami, Kenichiro,Tonogaki, Keisuke,Ohashi, Youichi,Yoshida, Jun-Ichi
, p. 4093 - 4096 (2007/10/03)
(Chemical Equation Presented) A catalytic one-pot triarylation on the C=C core of vinylboronate pinacol ester (1) produces extended π-systems based on a multisubstituted olefin structure very rapidly. We established an efficient protocol for the Pd-cataly
Solvolytic rearrangements of 2,2-Dianisyl-1-tolylvinyl Bromide and (E)- and (Z)-1,2-Dianisyl-2-tolylvinyl Bromide
Wanigasekera, Dave,Lee, Choi Chuck,Houminer, Yoram,Aviv, Michal,Rappoport, Zvi
, p. 4367 - 4373 (2007/10/02)
The solvolysis of 2,2-dianisyl-1-tolylvinyl bromide (3-Br) in AcOH-AgOAc, AcOH-NaOAc, or 2,2,2-trifluoroethanol (TFE)-2,6-lutidine gave complete rearrangement to (E)- and (Z)-1,2-dianisyl-2-tolylvinyl acetates or 2,2,2-trifluoroethyl ethers, respectively,