922523-50-0

Basic information

• Product Name: Methanesulfonic acid, 1,1,1-trifluoro-, (2S,4R)-2,4-dimethyl-1-methylene-5-(phenylmethoxy)pentyl ester
• CAS NO: 922523-50-0
• Molecular Formula: C16H21F3O4S
• Molecular Weight: 366.402
• Mol File: 922523-50-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methanesulfonic acid, 1,1,1-trifluoro-, (2S,4R)-2,4-dimethyl-1-methylene-5-(phenylmethoxy)pentyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Methanesulfonic acid, 1,1,1-trifluoro-, (2S,4R)-2,4-dimethyl-1-methylene-5-(phenylmethoxy)pentyl ester(922523-50-0)
• EPA Substance Registry System: Methanesulfonic acid, 1,1,1-trifluoro-, (2S,4R)-2,4-dimethyl-1-methylene-5-(phenylmethoxy)pentyl ester(922523-50-0)

Safety Data

• Hazardous Substances Data: 922523-50-0(Hazardous Substances Data)

Upstream product

• 643036-49-1 (2S,4R)-5-Benzyloxy-2,4-dimethyl-pentanoic acid ((1R,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl)-methyl-amide 
• 203454-44-8 (R)-4-Benzyl-3-((S)-3-benzyloxy-2-methyl-propionyl)-oxazolidin-2-one 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 
• 72297-80-4 1-[((S)-3-iodo-2-methylpropoxy)methyl]benzene 
• 3587-60-8 Benzyloxymethyl chloride 
• 922523-28-2 C₁₅H₂₂O₂ 
• 145100-51-2 N-(5-chloropyridin-2-yl)-1,1,1-trifluoro-N-[(trifluoromethyl)sulphonyl]methanesulphonamide 

Downstream Products

• 922523-29-3 C₁₉H₃₂OSi 
• 922523-33-9 C₃₃H₄₁NO₆ 

Relevant articles and documents

Synthesis of the southern FGHI ring system of azaspiracid-1 and investigation into the controlling elements of C28- and C36-ketalization

Heading south: An efficient approach to the FGHI southern ring system of azaspiracid-1 is disclosed. Each of the eight stereogenic centers is generated with excellent diastereoselectivity. In addition, the stereochemical outcome of the ketalization steps could be controlled by careful selection of the conditions. Teoc = 2-(trimethylsilyl)ethoxycarbonyl; TMS = trimethylsilyl; TIPS = triisopropylsilyl; Bn = benzyl. (Chemical Equation Presented).