924364-21-6Relevant articles and documents
Asymmetric synthesis of α-substituted aldehydes by Pd-catalyzed asymmetric allylic alkylation-alkene isomerization-Claisen rearrangement
Trost, Barry M.,Zhang, Ting
, p. 6007 - 6010 (2007/10/03)
(Chemical Equation Presented) Enantiospecific aliphatic Claisen rearrangement was realized with generally high chirality transfer. The requisite substrates were synthesized via Pd-catalyzed asymmetric allylic alkylation (AAA) from easily obtained starting