92527-07-6

Basic information

• Product Name: 1-(4-(dichloro-λ³-iodanyl)phenyl)ethan-1-one
• Synonyms: 1-(4-(dichloro-λ³-iodanyl)phenyl)ethan-1-one
• CAS NO: 92527-07-6
• Molecular Weight: 316.953
• Mol File: 92527-07-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(4-(dichloro-λ³-iodanyl)phenyl)ethan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-(dichloro-λ³-iodanyl)phenyl)ethan-1-one(92527-07-6)
• EPA Substance Registry System: 1-(4-(dichloro-λ³-iodanyl)phenyl)ethan-1-one(92527-07-6)

Safety Data

• Hazardous Substances Data: 92527-07-6(Hazardous Substances Data)

Upstream product

• 13329-40-3 4-Iodoacetophenone 

Downstream Products

• 13329-40-3 4-Iodoacetophenone 
• 684-16-2 Hexafluoroacetone 
• 832096-07-8 2,2-dichloro-1-(4-iodophenyl)ethan-1-one 
• 4209-04-5 2-chloro-1-(4-iodophenyl)ethan-1-one 
• 64297-70-7 1-(4-iodosyl-phenyl)-ethanone 

Relevant articles and documents

Synthesis of Benzoxazoles Using Electrochemically Generated Hypervalent Iodine

The indirect ("ex-cell") electrochemical synthesis of benzoxazoles from imines using a redox mediator based on the iodine(I)/iodine(III) redox couple is reported. Tethering the redox-active iodophenyl subunit to a tetra-alkylammonium moiety allowed for anodic oxidation to be performed without supporting electrolyte. The mediator salt can be easily recovered and reused. Our "ex-cell" approach toward the electrosynthesis of benzoxazoles is compatible with a range of redox-sensitive functional groups. An unprecedented concerted reductive elimination mechanism for benzoxazole formation is proposed on the basis of control experiments and DFT calculations.