92551-16-1

Basic information

• Product Name: Benzene, 1,1'-(1-chloro-2-methyl-1,2-ethanediyl)bis-
• CAS NO: 92551-16-1
• Molecular Formula: C15H15Cl
• Molecular Weight: 230.737
• Mol File: 92551-16-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, 1,1'-(1-chloro-2-methyl-1,2-ethanediyl)bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,1'-(1-chloro-2-methyl-1,2-ethanediyl)bis-(92551-16-1)
• EPA Substance Registry System: Benzene, 1,1'-(1-chloro-2-methyl-1,2-ethanediyl)bis-(92551-16-1)

Safety Data

• Hazardous Substances Data: 92551-16-1(Hazardous Substances Data)

Upstream product

• 4460-46-2 3-chloro-3-phenyl-3H-diazirine 
• 98-87-3 benzylidene dichloride 
• 60-29-7 diethyl ether 
• 676-58-4 methylmagnesium chloride 
• 34713-70-7 2-Phenylpropanal 
• 41997-47-1 1,1-diphenyl-2-propanol 
• 110-86-1 pyridine 
• 7719-09-7 thionyl chloride 
• 7693-84-7 (1RS,2SR)-1,2-diphenyl-propan-1-ol 
• 7693-84-7 (1RS,2RS)-1,2-diphenyl-propan-1-ol 
• 100-41-4 ethylbenzene 
• 28795-94-0 1,2-diphenyl-1-propanol 
• 781-35-1 1,1-diphenylacetone 
• 766-90-5 cis-1-phenyl-1-propylene 

Downstream Products

• 7693-84-7 (1R,2R)-1,2-diphenyl-propan-1-ol 
• 7693-84-7 (1S,2R)-1,2-diphenylpropan-1-ol 
• 779-51-1 cis-α-methylstilbene 
• 833-81-8 (E)-1,2-diphenylpropene 
• 7693-92-7 (1RS,2SR)-1-iodo-1,2-diphenyl-propane 

Relevant articles and documents

Indium-catalyzed direct chlorination of alcohols using chlorodimethylsilane-benzil as a selective and mild system

The InCl3-catalyzed reaction of alcohols with chlorodimethylsilane (HSiMe2Cl) in the presence of benzil gave the corresponding organic chlorides under mild conditions. Benzil significantly changes the reaction course because the reducing product through dehydroxyhydration was obtained in the absence of benzil. The secondary or tertiary alcohols were effectively chlorinated. The substrates bearing acid-sensitive functional groups were also applied to this system. The highly selective chlorination of the tertiary site was observed in the competitive reaction between tertiary and primary alcohols. The highly coordinated hydrosilane generated from benzil and HSiMe2Cl is an important intermediate. Copyright