92575-94-5Relevant articles and documents
Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation
Capaldo, Luca,Ravelli, Davide
, p. 2243 - 2247 (2021/04/05)
A versatile approach for the alkynylation of a variety of aliphatic hydrogen donors, including alkanes, is reported. We used tetrabutylammonium decatungstate as photocatalyst to generate organoradicals from C-H/Si-H bonds via hydrogen atom transfer. The l
Visible-Light-Induced Alkynylation of α-C–H Bonds of Ethers with Alkynyl Bromides without External Photocatalyst
Xie, Xiaofei,Liu, Jie,Wang, Lei,Wang, Min
, p. 1534 - 1538 (2019/09/06)
A direct alkynylation of C(sp3)–H bonds adjacent to an oxygen atom of ethers under visible light irradiation was developed in the absence of an external photocatalyst. The reaction of ethers and alkynyl bromides underwent smoothly to generate the corresponding products in good yields with excellent functional-group tolerance. Initial mechanistic experimental results indicated that the reaction may involve a free radical pathway.
Synthesis of 1,3-dioxacyclan-2-yl-substituted 1,2,3-triazoles
Zlotskii,Raskil’dina,Golovanov,Bormotin,Bekin
, p. 3 - 6 (2017/04/24)
A new method for preparing 4-(1,3-dioxacyclan-2-yl)-5-phenyl-1,2,3-triazoles in 30–75% yields has been developed on the basis of azide–alkyne cycloaddition to 2-phenylethinyl-1,3-dioxacyclanes. It has been shown that the best results are achieved when the reaction is carried out at 150–155°C in DMSO.