92577-90-7Relevant articles and documents
Regioselective hydrothiolation of alkenes bearing heteroatoms with thiols catalyzed by palladium diacetate
Tamai, Taichi,Ogawa, Akiya
, p. 5028 - 5035 (2014/06/23)
In sharp contrast to many examples of transition-metal-catalyzed hydrothiolation of alkynes, the corresponding catalytic addition of thiols to alkenes has remained undeveloped. However, a novel Pd-catalyzed addition of thiols to alkenes bearing a heteroatom, such as oxygen and nitrogen, is found to proceed under mild conditions to give the corresponding Markovnikov adducts, regioselectively, in good yields.
