92601-82-6Relevant articles and documents
AN INEXPENSIVE INFLUENCE MODIFICATION OF THE SIMMONS-SMITH REACTION: THE FORMATION OF BROMOMETHYLZINC BROMIDE AS STUDIED BY NMR SPECTROSCOPY
Fabisch, Bodo,Mitchell, Terence N.
, p. 219 - 222 (2007/10/02)
Bromomethylzinc bromide, prepared from zinc metal and methylene bromide in tetrahydrofuran, gives moderate to good yields of cyclopropanation product when treated with olefins, thus providing an inexpensive alternative to the Simmons-Smith procedure.An NMR study of the reaction between metallic zinc and methylene bromide has been carried out: in addition to bromomethylzinc bromide and dimethylzinc, two further species were observed and tentatively identified as bis(bromomethyl)zinc a di- or tri-zinc compound.