92610-81-6

Basic information

• Product Name: (R,R)-3-Propylthiiran-2-methanol
• Synonyms: (R,R)-3-Propylthiiran-2-methanol
• CAS NO: 92610-81-6
• Molecular Weight: 132.227
• Mol File: 92610-81-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R,R)-3-Propylthiiran-2-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (R,R)-3-Propylthiiran-2-methanol(92610-81-6)
• EPA Substance Registry System: (R,R)-3-Propylthiiran-2-methanol(92610-81-6)

Safety Data

• Hazardous Substances Data: 92610-81-6(Hazardous Substances Data)

Upstream product

• 89321-71-1 (2S,3S)-3-propyl-2-oxiranemethanol 

Downstream Products

• 90243-45-1 (2S,4S)-2-methyl-4-propyl-1,3-oxathiane 
• 90243-47-3 (2S,4R)-2-methyl-4-propyl-1,3-oxathiane 

Relevant articles and documents

A new one-step strategy for the stereochemical assignment of acyclic 2- and 3-sulfanyl-1-alkanols using the CD exciton chirality method

A new one-step strategy is described for the stereochemical assignment of acyclic 2- and 3-sulfanyl-1-alkanols using the CD exciton chirality method. Using the 9-anthroate chromophore for the derivatization of both functional groups, the resulting bisignate CD curves unequivocally allow the determination of the stereochemistry from a single CD measurement. The usefulness of the new method is demonstrated using synthesized optically pure 3-sulfanyl-1-hexanols and 2-sulfanyl-1-hexanols as model compounds. The developed microscale method is also useful for the stereochemical assignment of 1,2- and 1,3-diols. To our knowledge this is the first application of the CD exciton chirality method to acyclic 2- and 3-sulfanyl-1-alkanols.

Enantioselective Synthesis of (+)- and (-)-cis-2-methyl-4-propyl-1,3-oxathiane and their Olfactive Properties

The enantioselective synthesis of (+)- and (-)-cis-2-methyl-4-propyl-1,3-oxathiane 8 and 9 from (E)-2-hexen-1-ol (1) as common starting material is described.The two enantiomeric forms exhibit different organoleptic properties.