92644-16-1

Basic information

• Product Name: tert-butyl 2-(p-bromophenyl)hydrazine-1-carboxylate
• Synonyms: tert-butyl 2-(p-bromophenyl)hydrazine-1-carboxylate
• CAS NO: 92644-16-1
• Molecular Weight: 287.156
• Mol File: 92644-16-1.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: tert-butyl 2-(p-bromophenyl)hydrazine-1-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 2-(p-bromophenyl)hydrazine-1-carboxylate(92644-16-1)
• EPA Substance Registry System: tert-butyl 2-(p-bromophenyl)hydrazine-1-carboxylate(92644-16-1)

Safety Data

• Hazardous Substances Data: 92644-16-1(Hazardous Substances Data)

Upstream product

• 40400-13-3 2-Iodobenzyl bromide 
• 92846-10-1 tert-butyl 2-(4-bromophenyl)diazene-1-carboxylate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 622-88-8 4-bromophenylhydrazine hydrochloride 
• 106-40-1 4-bromo-aniline 
• 870-46-2 t-butoxycarbonylhydrazine 
• 589-15-1 1-bromomethyl-4-bromobenzene 

Downstream Products

• 1382978-06-4 (R)-3-[N-(4-bromobenzyl)-N'-t-butoxycarbonylhydrazino]-2-hydroxypropionic acid methyl ester 
• 1432502-66-3 (R)-3-[N-(5'-chloro-2'-fluorobiphenyl-4-ylmethyl)hydrazino]-2-hydroxypropionic acid 2-oxo-2-phenylethyl ester 
• 1432502-70-9 (R)-3-[N-(5'-chloro-2'-fluorobiphenyl-4-ylmethyl)hydrazino]-2-hydroxypropionic acid 2-oxo-2-phenylethyl ester 
• 1259224-11-7 5-bromo-2,3-diphenyl-1H-indole 
• 13041-70-8 (E)-4-bromostilbene 
• 1260148-05-7 5-bromo-2-methyl-3-phenyl-1H-indole 
• 21865-50-9 6-bromo-1,2,3,4-tetrahydro-9H-carbazole 
• 3650-78-0 methyl (E)-4-bromocinnamate 

Relevant articles and documents

Palladium/copper-catalyzed arylation of alkenes with N′-acyl arylhydrazines

A novel ligand-free palladium/copper-catalyzed Heck-type coupling reaction of alkenes and N′-acyl arylhydrazines has been developed by using air as the terminal oxidant. This protocol features wide functional group tolerance and produces highly chemoselective and regioselective products with good to excellent yields.

Selective Functionalization of Graphene at Defect-Activated Sites by Arylazocarboxylic tert-Butyl Esters

The development of versatile functionalization concepts for graphene is currently in the focus of research. Upon oxo-functionalization of graphite, the full surface of graphene becomes accessible for C?C bond formation to introduce out-of-plane functional

Microwave-Assisted Rapid One-Pot Synthesis of Fused and Non-Fused Indoles and 5-[18F]Fluoroindoles from Phenylazocarboxylates

Substituted indoles can be prepared from phenylazocarboxylates through a rapid one-pot sequence featuring a microwave-assisted Fischer indole synthesis as a key step. Considering that the phenylazocarboxylates may beforehand be modified by mild nucleophilic aromatic substitution, including the introduction of [18F]fluoride, the overall strategy offers an attractive new access to 5-[18F]fluoroindoles.