92740-87-9Relevant articles and documents
Molecular engineering of phenothiazine-based monomer and dimer hole transport materials and their photovoltaic performance
Zhai, Mengde,Miao, Yawei,Chen, Cheng,Wang, Haoxin,Ding, Xingdong,Wu, Cheng,Yang, Xichuan,Cheng, Ming
, (2021)
Through molecular engineering, phenothiazine-based monomer hole transport material (HTM) PTZT and dimer HTM D-PTZT were designed and synthesized. The photoelectrochemical properties are significantly influence by the adjustment of the molecular structure. Applied in perovskite solar cells (PSCs), monomer HTM PTZT-based device achieves the highest efficiency of 18.74% while only 15.45% for dimer HTM D-PTZT-based device under 100 mW cm?2 AM 1.5G solar illumination.
C-to N-Center Remote Heteroaryl Migration via Electrochemical Initiation of N Radical by Organic Catalyst
Liu, Chengkou,Jiang, Qiang,Lin, Yang,Fang, Zheng,Guo, Kai
supporting information, p. 795 - 799 (2020/02/04)
Herein an exogenous oxidant- A nd metal-free electrochemical heteroaryl migration triggered by N radicals to construct new N-C bonds was developed. This methodology features a high atom economy and utilization rate of energy, and it is insensitive to water and air. Moreover, a user-friendly undivided cell was employed. The use of an organic catalyst makes it more efficient, green, and practical.
Insights on bimetallic micellar nanocatalysis for buchwald-hartwig aminations
Ansari, Tharique N.,Taussat, Armand,Clark, Adam H.,Nachtegaal, Maarten,Plummer, Scott,Gallou, Fabrice,Handa, Sachin
, p. 10389 - 10397 (2019/10/14)
A nanocatalyst for micellar Buchwald-Hartwig aminations is developed, thoroughly characterized, and applied on a variety of substrates. The catalyst is stable under ambient conditions for at least six months. The catalyst retained its activity after several cycles, and its structure remained intact as confirmed by NMR spectroscopy. Association of Pd nanoparticles with Cu by a phosphine ligand is revealed by 31P NMR spectroscopy, and their linkage with the activated carbon surface is revealed by XAS analysis. Control NMR experiments revealed the binding of the ligand with both Cu and Pd, and all phosphine molecules are under the same environment. In addition to NMR and XAS analysis, the catalyst is characterized by SEM, HRTEM, XPS, and TGA. Reactions are highly reproducible at variable scales. Environmentally benign, proline-based amphiphile PS-750-M is critical for catalytic activity, which is achieved under mild conditions in water as the reaction medium. The inherent sustainability of these conditions coupled with a low E factor achievable through robust recycling of catalyst and reaction medium demonstrates the significant utility of this technology.
