92749-15-0

Basic information

• Product Name: Heptane, 7-bromo-1-(methylsulfinyl)-1-(methylthio)-
• CAS NO: 92749-15-0
• Molecular Formula: C9H19BrOS2
• Molecular Weight: 287.285
• Mol File: 92749-15-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Heptane, 7-bromo-1-(methylsulfinyl)-1-(methylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: Heptane, 7-bromo-1-(methylsulfinyl)-1-(methylthio)-(92749-15-0)
• EPA Substance Registry System: Heptane, 7-bromo-1-(methylsulfinyl)-1-(methylthio)-(92749-15-0)

Safety Data

• Hazardous Substances Data: 92749-15-0(Hazardous Substances Data)

Upstream product

• 629-03-8 1 ,6-dibromohexane 
• 33577-16-1 methyl methylsulfinylmethyl sulfide 

Relevant articles and documents

A Versatile Synthesis of Four-, Five-, and Six-membered Cyclic Ketones Using Methyl Methylthiomethyl Sulfoxide

Cyclization of 1,n-dihaloalkanes with methyl methylthiomethyl sulfoxide in the presence of a base (n-BuLi or KH) gave three-, four-, five-, and six-membered 1-methylsulfinyl-1-methylthiocycloalkanes.These cyclization products were easily converted to the corresponding ketones by acid hydrolysis except 1-methylsulfinyl-1-methylthiocyclopropane which afforded a complicated mixture.The combination of the cyclization with the acidhydrolysis thus provides a new method for synthesizing four-, five-, and six-membered cycloalkanones.Several representative preparations, such as those of substituted cyclobutanones, 3-cyclopentanone, and tetrahydro-4-pyrone are described.