928642-45-9

Basic information

• Product Name: 6-diazo-2-cyclohexen-1-one
• Synonyms: 6-diazo-2-cyclohexen-1-one
• CAS NO: 928642-45-9
• Molecular Weight: 122.126
• Mol File: 928642-45-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 6-diazo-2-cyclohexen-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 6-diazo-2-cyclohexen-1-one(928642-45-9)
• EPA Substance Registry System: 6-diazo-2-cyclohexen-1-one(928642-45-9)

Safety Data

• Hazardous Substances Data: 928642-45-9(Hazardous Substances Data)

Upstream product

• 930-68-7 cyclohexenone 
• 407-38-5 2,2,2-trifluoroethyl trifluoroacetate 

Downstream Products

• 928642-46-0 (S)-6-triphenylsilylcyclohex-2-enone 
• 132-64-9 dibenzofuran 
• 108-95-2 phenol 
• 1629168-55-3 methyl 2-((2-hydroxyphenyl)amino)benzoate 
• 2391-71-1 2-(2-hydroxyphenlylamino)phenol 
• 1629168-54-2 2-((3-nitrophenyl)amino)phenol 
• 1129255-51-1 2-((4-bromophenyl)amino)phenol 
• 1629168-53-1 2-((3-bromophenyl)amino)phenol 
• 1629168-52-0 2-((2-bromophenyl)amino)phenol 
• 87671-67-8 2-[(4-methylphenyl)amino]phenol 
• 92028-38-1 2-(o-tolylamino)phenol 
• 107455-62-9 N-(2-methoxyphenyl)-4-methylaniline 
• 644-71-3 2-(phenylamino)phenol 
• 1613145-61-1 6-(phenylamino)cyclohex-2-enone 

Relevant articles and documents

Studies of the stereochemistry of [2+2]-photocycloaddition reactions of 2-cyclohexenones with olefins

(Chemical Equation Presented) Stereochemical studies of the photocycloaddition of a chiral α,β-enone and isobutylene lead to a working hypothesis for the geometry of the 3(π-π*) excited state of the enone.

Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones

A novel silver(I)-catalyzed ring-contractive rearrangement of 5-substituted 6-diazo-2-cyclohexenones has been developed, providing a new and efficient access to 5-alkylidene-2-cyclopentenones. The AgOTf-catalyzed reaction proceeds through metal-carbenoid formation followed by endocyclic allyl [1,2] migration with excellent stereoselectivity and broad substrate scope.