929083-12-5

Basic information

• Product Name: NiBr(P(C₆H₅)3)(SC₆H₃CH₃C(C₆H₃(CF₃)2)NC₆H₄CH₃)
• CAS NO: 929083-12-5
• Molecular Weight: 853.328
• Mol File: 929083-12-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: NiBr(P(C₆H₅)3)(SC₆H₃CH₃C(C₆H₃(CF₃)2)NC₆H₄CH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: NiBr(P(C₆H₅)3)(SC₆H₃CH₃C(C₆H₃(CF₃)2)NC₆H₄CH₃)(929083-12-5)
• EPA Substance Registry System: NiBr(P(C₆H₅)3)(SC₆H₃CH₃C(C₆H₃(CF₃)2)NC₆H₄CH₃)(929083-12-5)

Safety Data

• Hazardous Substances Data: 929083-12-5(Hazardous Substances Data)

Upstream product

• 36673-36-6 dibromobis(triphenylphosphine)nickel(II) 

Relevant articles and documents

Platinum group thiophenoxyimine complexes: syntheses and crystallographic/computational studies

Monomeric thiosalicylaldiminate complexes of rhodium(I) and iridium(I) were prepared by ligand transfer from the homoleptic zinc(II) species. In the presence of strongly donating ligands, the iridium complexes undergo insertion of the metal into the imine carbon-hydrogen bond. Thiophenoxyketimines were prepared by nontemplated reaction of o-mercaptoacetophenone with anilines and were complexed with rhodium(I), iridium(I), nickel(II), and platinum(II). X-ray crystallographic studies showed that while the thiosalicylaldiminate complexes display planar ligand conformations, those of the thiophenoxyketiminates are strongly distorted. Results of a computational study predicted that all synthetically accessible thiophenoxyketiminates will display distorted geometries.