92929-51-6Relevant articles and documents
Regioselective Functionalization of Alkyl Aryl Ethers
Chawla, H. Mohindra,Pathak, Manisha
, p. 1092 - 1093 (2007/10/02)
A new procedure for regioselective functionalization of sensitive alkyl aryl ethers has been proposed as an alternative to picrate and sulphonamide derivatives.The procedure is based upon their reaction with cerium(IV) ammonium nitrate (CAN) and gives good yields of nitro substituted ethers, affording one pot synthesis of hitherto unknown 1-isopropoxy-4-nitronaphthalene, 1-butoxy-4-nitronaphthalene, 2-isopropoxy-6-nitronaphthalene and 2-butoxy-6-nitronaphthalene.A plausible mechanism has been suggested.
Cerium (IV) Induced Functionalization of Naphthyl Esters
Chawla, H. Mohindra,Mittal, Ram S.
, p. 899 - 900 (2007/10/02)
A mild but efficient method for the drivatization of esters has been developed by their reaction with cerium(IV)ammonium nitrate in acetic acid medium.The method provides a facile synthesis of 2-nitro-, 5-nitro-1-napthyl acetates, 4-nitro-1-naphthylbenzoa