92934-83-3

Basic information

• Product Name: (2R,3R)-3-((R)-1-Phenyl-ethoxy)-butan-2-ol
• Synonyms: (2R,3R)-3-((R)-1-Phenyl-ethoxy)-butan-2-ol
• CAS NO: 92934-83-3
• Molecular Weight: 194.274
• Mol File: 92934-83-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,3R)-3-((R)-1-Phenyl-ethoxy)-butan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R)-3-((R)-1-Phenyl-ethoxy)-butan-2-ol(92934-83-3)
• EPA Substance Registry System: (2R,3R)-3-((R)-1-Phenyl-ethoxy)-butan-2-ol(92934-83-3)

Safety Data

• Hazardous Substances Data: 92934-83-3(Hazardous Substances Data)

Upstream product

• 75281-80-0 4,5-dimethyl-2-phenyl-(2α,4α,5β)-1,3-dioxolane 
• 122045-47-0 R,R-2,4,5 trimethyl dioxolane 
• 100-52-7 benzaldehyde 

Relevant articles and documents

BORON FLUORIDE PROMOTED CLEAVAGE OF ACETALS BY ORGANOCOPPER REAGENTS. APPLICATION TO ASYMMETRIC SYNTHESIS

In the presence of BF3*Et2O, organocopper and cuprate reagents promote the substitution of one alkoxy group of an acetal.Under the same conditions, alkoxy tetrahydropyrans react selectively, by ring cleavage.Chiral cyclic acetals, having a C2 axis of symmetry are diastereoselectively cleaved.The method serves to synthesize chiral secondary alcohols, after the removal of the chiral auxiliary.