929878-91-1Relevant articles and documents
A general metal-assisted synthesis of α-halo oxime ethers from nitronates and nitro compounds
Sukhorukov, Alexey Yu.,Kapatsyna, Maria A.,Yi, Tammy Lim Ting,Park, Hyeong Ryool,Naumovich, Yana A.,Zhmurov, Petr A.,Khomutova, Yulia A.,Ioffe, Sema L.,Tartakovsky, Vladimir A.
, p. 8148 - 8159 (2015/02/05)
An approach to the synthesis of α-halo oxime ethers from readily accessible nitronates and nitro compounds via bis-(oxy)enamines is reported. A key step of the strategy involves the unprecedented reaction of bis(oxy)enamines with a metal (Co, Zn, Mg, Mn)
Synthesis and reactions of 3-halomethyl-substituted oxazine N-oxides
Mikhaylov, Andrey A.,Dilman, Alexander D.,Kunetsky, Roman A.,Khomutova, Yulia A.,Struchkova, Marina I.,Korlyukov, Alexander A.,Ioffe, Sema L.,Tartakovsky, Vladimir A.
supporting information; experimental part, p. 1038 - 1040 (2010/04/05)
A series of 3-halomethyl-5,6-dihydro-1,2-oxazine N-oxides (halogen = Cl, Br, I) is prepared from 4-phenyl-3,6,6-trimethyl-5,6-dihydro-4H-oxazine N-oxide by means of a silylation/halogenation sequence. The obtained halogenated N-oxides undergo reactions typical of cyclic six-membered nitronates including 1,3-dipolar cycloaddition, addition of nucleophiles, and substitution of the halogen by C-, S-, and N-nucleophiles.
